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Spremembe odpornosti lesa zaradi izpiranja biološko aktivnih učinkovin in sprememb morfologije površine kot posledice vremenskih vplivov
ID Keržič, Eli (Author), ID Humar, Miha (Mentor) More about this mentor... This link opens in a new window, ID Vek, Viljem (Comentor)

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Abstract
V pričujoči doktorski disertaciji smo raziskali vpliv več dejavnikov, ki jih povzročajo vremenski vplivi, na odpornost različno odpornih lesnih vrst ter modificiranega in zaščitenega lesa. S pomočjo konfokalne mikroskopije smo določali hrapavost površin staranih vzorcev ter njihovo kolonizacijo z glivami modrivkami. S hrapavostjo na mikroskopskem nivoju, določeno pri 50× povečavi, smo uspeli do neke mere pojasniti spremembe odpornosti proti navlaževanju lesa zaradi vremenskih vplivov. Pri termično modificiranem lesu je v skladu z Wenzlovo teorijo povečanje hrapavosti povzročilo zmanjšanje kontaktnega kota, kot je značilno za hidrofilne površine. Nasprotno se je kontaktni kot na hidrofobni površini z voskom obdelanega termično modificiranega lesa ob povečanju hrapavosti povečal. Staranim in kontrolnim vzorcem smo določili odpornost proti nekaterim glivam razkrojevalkam ter odpornost proti navlaževanju. Oba parametra sta nam služila za izračun relativne življenjske dobe testiranih materialov. Pri večini odpornih oz. zmerno odpornih materialov so se izgube mase, ki so jih povzročile glive (T. versicolor, G. trabeum in R. placenta), s staranjem povečale. Poslabšanje inherentne odpornosti je sovpadalo z zmanjšano vsebnostjo ekstraktivnih snovi. Vremenski vplivi so negativno vplivali tudi na odpornost proti navlaževanju, kar se je odrazilo v skrajšanju relativne življenjske dobe pri vseh testiranih materialih. Odpornost se je najbolj ohranila pri jedrovini robinije, ki je tudi po 40 letih uporabe v zunanjem okolju vsebovala primerljive oz. celo nekoliko višje koncentracije ekstraktivov kot svež les. Na drugi strani se je odpornost najbolj poslabšala jedrovini rdečega bora.

Language:Slovenian
Keywords:hrapavost, inherentna odpornost, odpornost proti navlaževanju, ekstraktivi, biocidi, izpiranje
Work type:Doctoral dissertation
Typology:2.08 - Doctoral Dissertation
Organization:BF - Biotechnical Faculty
Publisher:[E. Keržič]
Year:2024
PID:20.500.12556/RUL-163154 This link opens in a new window
UDC:630*842.9:630*813.2(043.2)
COBISS.SI-ID:210255107 This link opens in a new window
Publication date in RUL:03.10.2024
Views:115
Downloads:28
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Secondary language

Language:English
Title:Changes in wood durability due to leaching of biologically active substances and changes in surface morphology resulting from weathering
Abstract:
This dissertation investigated the influence of various weathering factors on the durability of differently durable wood species, modified and protected wood. Confocal microscopy was used to determine the surface roughness of the weathered samples and their colonisation with blue stain fungi. The changes in the wettability of the wood due to weathering could be explained to a certain extent by the roughness at the microscopic level, which was determined at 50x magnification. According to Wenzel's theory, an increase in the roughness of thermally modified wood led to a decrease in the contact angle, as is typical for hydrophilic surfaces. In contrast, the contact angle on the hydrophobic surface of wax-treated, thermally modified wood increased with increasing roughness. In addition, the resistance to some decay fungi and the resistance to wetting of the weathered and control samples were determined. Both parameters were used to calculate the relative resistance dose of the tested materials. For most of the durable or moderately durable materials, the mass losses caused by fungi (T. versicolor, G. trabeum and R. placenta) increased with weathering. The deterioration in inherent durability coincided with the reduced extractives content. Weathering also had a negative effect on the wetting ability, which was reflected in the reduction of the relative resistance dose of all tested materials. Durability was best preserved in the heartwood of black locust, which even after 40 years of outdoor use contained a comparable or even slightly higher concentration of extractives than fresh wood. On the other hand, the resistance of Scots pine heartwood deteriorated the most.

Keywords:roughness, inherent durability, wetting ability, extractives, biocides, leaching

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