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Vpliv velikosti gradnikov in deleža protipožarnega sredstva na lastnosti ivernih plošč brez formaldehida
ID Kopač, Luka (Author), ID Medved, Sergej (Mentor) More about this mentor... This link opens in a new window, ID Lesar, Boštjan (Comentor)

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Abstract
Uporaba ivernih plošč za izdelavo pohištva je v današnjem času zelo razširjena, manj se uporabljajo v konstrukcijske namene. Eden od razlogov je slaba odpornost ivernih plošč proti gorenju, ki jo lahko izboljšamo z uporabo zaviralcev gorenja. Dodatek le-teh ima pogosto negativen vpliv na mehanske lastnosti, poleg tega se pri gorenju, zaradi rabe lepil na osnovi formaldehida, še dodatno poveča emisija formaldehida. Raziskovali smo učinkovitost kombinacije citronske kisline in sorbitola kot veziva ter amonijevega dihidrogenfosfata kot zaviralca ognja, na protipožarne in upogibne lastnosti ivernih plošč ter njihovo razslojno trdnost in odpornost na vodo. Poskušali smo izdelati iverno ploščo z najboljšimi lastnostmi protipožarnega delovanja in hkrati s čim manjšim poslabšanjem trdnosti. Z večjim deležem veziva so se lastnosti izboljšale, medtem ko velikost gradnikov ni igrala pomembne vloge. Dodatek amonijevega dihidrogenfosfata je izboljšal odpornost na vodo, ampak imel negativen vpliv na mehanske lastnosti. Najbolj optimalen delež dodanega zaviralca gorenja je bil 5 %. Pri preizkusu na vroči plošči smo ugotovili večjo izgubo mase pri vzorcih z dodanim amonijevim dihidrogenfosfatom, domnevno zaradi njegovega razpada pri povišani temperaturi. Predvidevamo, da razpadni produkti ščitijo ploščo pred ognjem, kar je bilo razvidno pri izpostavitvi plamenu na robu preizkušanca.

Language:Slovenian
Keywords:Iverna plošča, citronska kislina, amonijev dihidrogenfosfat, zaviralec ognja
Work type:Master's thesis/paper
Typology:2.09 - Master's Thesis
Organization:BF - Biotechnical Faculty
Publisher:[L. Kopač]
Year:2024
PID:20.500.12556/RUL-161849 This link opens in a new window
UDC:630*862.1:843.1
COBISS.SI-ID:207588867 This link opens in a new window
Publication date in RUL:15.09.2024
Views:116
Downloads:528
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Secondary language

Language:English
Title:The effect of particle size and fire retardant share on properties of formaldehyde-free particle boards
Abstract:
The use of particleboards for the manufacture of furniture is very common, but they are used less often for structural purposes. One of the reasons is the poor fire safety of particleboards, which can be improved using fire retardants. However, their addition often has a negative impact on the boards' mechanical properties, and using formaldehyde-based adhesives increases emissions during a fire. The objective was to investigate the efficacy of citric acid and sorbitol as an adhesive and ammonium dihydrogen phosphate as a fire retardant. The properties measured were fire retardancy, MOR, MOE, IB and moisture resistance. In several steps we tried manufacturing a board with the best fire retardant properties with as little deterioration of strength as possible. The properties improved with a higher proportion of binder, while the size of the particles did not play a significant role. The addition of ammonium dihydrogen phosphate improved moisture resistance but had a negative effect on mechanical properties. The optimal proportion of fire retardant was 5 wt%. In the hot plate test a greater mass loss was recorded in samples with added ammonium dihydrogen phosphate, presumably due to its decomposition at elevated temperature. The resulting products seemed to protect boards when exposed to flame impingement on the sample's edge.

Keywords:particleboard, citric acid, ammonium dihydrogen phosphate, fire retardant

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