Sinteza nikljevih koordinacijskih spojin z izbranimi piritioni

Polak, Jan (author), Turel, Iztok (mentor)

Namen diplomske naloge je bil sintetizirati koordinacijske spojine niklja(II) s triflourometil substituiranimi piritioni. Piritione sem sintetiziral dvostopenjsko iz 2-kloro piridinov. Pripravljene produkte sem uporabil kot ligande za sintezo nikljevih koordinacijskih spojin. Vse nastale spojine sem karakteriziral z jedrsko magnetno resonanco (NMR), IR spektroskopijo, UV-Vis spektroskopijo, CHN elementno analizo in masno spektroskopijo visoke ločljivosti (HRMS). Iz določenih spojin sem pripravil monokristale, ki so bili analizirani z rentgensko difrakcijo (XRD).

• Language: Slovenian
• Keywords: pirition, nikelj, sinteza, karakterizacija
• Work type: Bachelor thesis/paper
• Typology: 2.11 - Undergraduate Thesis
• Organization: FKKT - Faculty of Chemistry and Chemical Technology
• Year: 2024
• PID: 20.500.12556/RUL-161249
• COBISS.SI-ID: 207265283
• Publication date in RUL: 09.09.2024

Secondary language

• Language: English
• Title: Synthesis of nickel coordination compounds with selected pyrithiones

Abstract

The purpose of my thesis was to synthesize nickel coordination compounds with trifuoromethyl substituted pyrithiones. I synthesized the pyrithiones in two steps from 2-chloro pyridines. I used the prepared products as ligands for the formation of nickel coordination compounds. I characterized the resulting compounds with nuclear magnetic resonance (NMR), IR spectroscopy, UV-Vis spectroscopy, CHN elemental analysis and high resolution mass spectroscopy (HRMS). I obtained single crystals of certain compounds, which were analysed with X-ray diffraction (XRD).

• Keywords: pyrithione, nickel, synthesis, characterization