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Vpliv ionskih tekočin na Krafftovo temperaturo surfaktantov
ID Jaklič, Iza (Author), ID Šarac, Bojan (Mentor) More about this mentor... This link opens in a new window

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Abstract
Namen diplomske naloge je bil preučiti, kako dodatek treh ionskih tekočin ([MMIM]Cl, [EMIM]Cl, [BMIM]Cl) vpliva na Krafftovo temperaturo (TK) natrijevega dodecil sulfata (SDS). Vrednost TK sem določala z merjenjem specifične električne prevodnosti raztopin v odvisnosti od temperature. Prvo sem določila vrednosti TK za 20, 30 in 40 mM SDS v vodi in nato za 40 mM SDS v 0,01 M raztopini ionskih tekočin. Ugotovila sem, da ionske tekočine znižajo vrednost TK ter da [BMIM]Cl, ki ima najdaljšo alkilno verigo, najbolj zniža TK zaradi največjega hidrofobnega značaja ionske tekočine. Rezultate za SDS v vodi sem primerjala z vrednostmi iz literature in ugotovila, da je vrednost TK, ki sem jo določila, nižja od literaturne vrednosti. Odstopanje sem pripisala drugačnim eksperimentalnim pogojem in potencialno nečisti kemikaliji.

Language:Slovenian
Keywords:Ionske tekočine, surfaktanti, Krafftova temperatura
Work type:Bachelor thesis/paper
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2024
PID:20.500.12556/RUL-161037 This link opens in a new window
Publication date in RUL:06.09.2024
Views:108
Downloads:25
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Secondary language

Language:English
Title:The impact of ionic liquids on the Krafft temperature of surfactants
Abstract:
The aim of this thesis was to examine how the addition of three ionic liquids ([MMIM]Cl, [EMIM]Cl, [BMIM]Cl) affects the Krafft temperature (TK) of sodium dodecyl sulfate (SDS). I determined TK by measuring the specific electrical conductivity of solutions as a function of temperature. First, I determined the TK values for 20, 30, 40 mM SDS in a 0,01 M solution of ionic liquids. I found that the ionic liquids lowered the TK value and that [BMIM]Cl, which has the longest alkyl chain, reduced TK the most due to the highest hydrofobic character of the ionic liquid. I compared the results for SDS in water with values from the literature and found that the TK value I determined was lower than the literature value. I attributed this deviation to different experimental conditions and potentially impure chemicals.

Keywords:Ionic liquids, surfactants, Krafft temperature

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