Recent advances in the nickel-catalyzed alkylation of C-H bonds

Požgan, Franc (avtor), Grošelj, Uroš (avtor), Svete, Jurij (avtor), Štefane, Bogdan (avtor), Al Mamari, Hamad (avtor)

Functionalization of C-H bonds has emerged as a powerful strategy for converting inert, nonfunctional C-H bonds into their reactive counterparts. A wide range of C-H bond functionalization reactions has become possible by the catalysis of metals, typically from the second row of transition metals. First-row transition metals can also catalyze C-H functionalization, and they have the merits of greater earth-abundance, lower cost and better environmental friendliness in comparison to their second-row counterparts. C-H bond alkylation is a particularly important C-H functionalization reaction due to its chemical significance and its applications in natural product synthesis. This review covers Ni-catalyzed C-H bond alkylation reactions using alkyl halides and olefins as alkyl sources.

• Jezik: Angleški jezik
• Ključne besede: nickel, C-H activation, catalysis, C-H bond functionalization, C-H bond alkylation, Ni-catalysis, chelation assistance, cyclometalation
• Vrsta gradiva: Članek v reviji
• Tipologija: 1.02 - Pregledni znanstveni članek
• Organizacija: FKKT - Fakulteta za kemijo in kemijsko tehnologijo
• Status publikacije: Objavljeno
• Različica publikacije: Objavljena publikacija
• Leto izida: 2024
• Št. strani: 27 str.
• Številčenje: Vol. 29, iss. 9, art. 1917
• PID: 20.500.12556/RUL-158451
• UDK: 547:66.095.253:546.74
• ISSN pri članku: 1420-3049
• DOI: 10.3390/molecules29091917
• COBISS.SI-ID: 198576899
• Datum objave v RUL: 12.06.2024

Gradivo je del revije

• Naslov: Molecules
• Skrajšan naslov: Molecules
• Založnik: MDPI
• ISSN: 1420-3049
• COBISS.SI-ID: 18462981

Licence

• Licenca: CC BY 4.0, Creative Commons Priznanje avtorstva 4.0 Mednarodna
• Povezava: http://creativecommons.org/licenses/by/4.0/deed.sl
• Opis: To je standardna licenca Creative Commons, ki daje uporabnikom največ možnosti za nadaljnjo uporabo dela, pri čemer morajo navesti avtorja.

Sekundarni jezik

• Jezik: Slovenski jezik
• Ključne besede: nikelj, C-H aktivacija, kataliza

Projekti

• Financer: ARRS - Agencija za raziskovalno dejavnost Republike Slovenije
• Številka projekta: P1-0179
• Naslov: Napredna organska sinteza in kataliza