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Sinteza izbranih enaminoketonov in njihova uporaba v določenih fotokemijskih pretvorbah
ID Jarc Rydzi, Matej (Author), ID Svete, Jurij (Mentor) More about this mentor... This link opens in a new window

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Abstract
Enaminoketoni so pomembna skupina organskih spojin, ki nastopajo v mnogih reakcijah organske sinteze, kot je na primer sinteza heterocikličnih spojin. Iz enaminoketonov lahko pripravimo β-ketoiminatne komplekse. Ti kompleksi imajo zanimive optične lastnosti, kar nakazuje tudi na njihovo možno uporabnost v fotokemijskih transformacijah, ki so zaenkrat slabo raziskane. Zato sem poskusil razviti nove fotokemijske pretvorbe teh spojin. Ker so bile te reakcije le delno uspešne, sem se osredotočil na izhodne enaminoketone kot substrate za fotokemijske pretvorbe. Na tem področju sem bil bolj uspešen in sem naredil začetne poskuse za razvoj novih fotokemijskih transformacij na teh spojinah. Hkrati sem enaminoketone reagiral s klorosulfonil izocianatom, da sem pridobil substrate za fotoredoks reakcije.

Language:Slovenian
Keywords:enaminoketoni, β-ketoiminatni kompleksi, fotokemija, fotoredoks pretvorbe
Work type:Master's thesis/paper
Typology:2.09 - Master's Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2024
PID:20.500.12556/RUL-156103 This link opens in a new window
COBISS.SI-ID:195796483 This link opens in a new window
Publication date in RUL:08.05.2024
Views:501
Downloads:79
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Secondary language

Language:English
Title:Synthesis of selected enaminoketones and their use in different photochemical transformations
Abstract:
Enaminoketones are an important class of organic compounds with versatile applicability in organic synthesis, in particular in the synthesis of heterocyclic compounds. β-Ketoiminate complexes can be derived from the aforementioned compounds. These complexes have interesting optical properties, which suggest their possible use as substrates in photochemical transformations, which remain under-examined. This led to the attempt to develop new photochemical transformations of these compounds. Unfortunately, despite efforts, this achievement was elusive, thus I decided to focus on the starting enaminoketones as potential substrates for photochemical transformations. The efforts were successful, and the groundwork was laid for the development of novel photochemical reactions of these compounds. In parallel with the main topic, the aforementioned compound was reacted with chlorosulfonyl isocyanate, thus producing potential substrates for photoredox reactions.

Keywords:enaminoketones, β-ketoiminate complexes, photochemistry, photoredox conversions

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