Sinteza in karakterizacija srebrovih kompleksov s spiro analogom tiosečnine

Mesec, Gašper (author), Kljun, Jakob (mentor)

V diplomskem delu sem preizkusil sintezne metode za pripravo srebrovih kompleksov s spiroanalogom tiosečnine, ki jih je v sklopu svojega diplomskega dela predlagal Marko Bunarkić. Poskusil sem sintetizirati komplekse srebra in cikloheksil triazolidintiona v razmerjih 1:4 in 1:3, srebra, cikloheksil triazilidintiona in fenantrolina v razmerju 1:1:1 ter srebra, cikloheksil triazilidintiona in trifenilfosfina v razmerju 1:1:1. Kompleks s trifenilfosfinom mi je uspelo sintentizirati, pri ostalih kompleksih so nastali drugačni produkti od pričakovanih.

• Language: Slovenian
• Keywords: srebro, srebrovi kompleksi, 2-metiltiosemikarbazid, cikloheksil triazilidintion
• Work type: Bachelor thesis/paper
• Typology: 2.11 - Undergraduate Thesis
• Organization: FKKT - Faculty of Chemistry and Chemical Technology
• Year: 2024
• PID: 20.500.12556/RUL-155678
• COBISS.SI-ID: 192385539
• Publication date in RUL: 11.04.2024

Secondary language

• Language: English
• Title: Synthesis and characterization of silver complexes with a spyro analog of thiourea

Abstract

In my thesis I tested the synthetic methods for the preparation of silver complexes with the thiourea spiroanalogue proposed by Marko Bunarkić as part of his thesis. I attempted to synthesise complexes of silver and cyclohexyl triazolidinedione in 1:4 and 1:3 ratios, silver, cyclohexyl triazolidinedione and phenanthroline in 1:1:1 ratio and silver, cyclohexyl triazolidinedione and triphenylphosphine in 1:1:1 ratio. I was able to synthesise the complex with triphenylphosphine, but the other syntheses resulted in different products than expected.

• Keywords: Silver, Silver complexes, 2-Methylthiosemicarbazide, Cyclohexyl trializidinethione