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Carbonyl-supported coordination in imidazolates : a platform for designing porous nickel-based ZIFs as heterogeneous catalysts
ID
Škrjanc, Aljaž
(
Author
),
ID
Jankovič, Dominik
(
Author
),
ID
Meden, Anton
(
Author
),
ID
Mazaj, Matjaž
(
Author
),
ID
Svensson Grape, Erik
(
Author
),
ID
Gazvoda, Martin
(
Author
),
ID
Zabukovec Logar, Nataša
(
Author
)
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https://onlinelibrary.wiley.com/doi/10.1002/smll.202305258
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Abstract
Zeolitic imidazolate frameworks (ZIFs) are a subclass of metal–organic framework that have attracted considerable attention as potential functional materials due to their high chemical stability and ease of synthesis. ZIFs are usually composed of zinc ions coordinated with imidazole linkers, with some other transition metals, such as Cu(II) and Co(II), also showing potential as ZIF-forming cations. Despite the importance of nickel in catalysis, no Ni-based ZIF with permanent porosity is yet reported. It is found that the presence and arrangement of the carbonyl functional groups on the imidazole linker play a crucial role in completing the preferred octahedral coordination of nickel, revealing a promising platform for the rational design of Ni-based ZIFs for a wide range of catalytic applications. Herein, the synthesis of the first Ni-based ZIFs is reported and their high potential as heterogeneous catalysts for Suzuki–Miyaura cross-coupling C─C bond forming reactions is demonstrated.
Language:
English
Keywords:
heterogeneous catalysis
,
nickel catalysis
,
Suzuki–Miyaura cross coupling
,
zeolitic imidazolate frameworks
Work type:
Article
Typology:
1.01 - Original Scientific Article
Organization:
FKKT - Faculty of Chemistry and Chemical Technology
Publication status:
Published
Publication version:
Version of Record
Year:
2024
Number of pages:
7 str.
Numbering:
Vol. 20, iss. 6, art. 202305258
PID:
20.500.12556/RUL-154414
UDC:
620.1/.2
ISSN on article:
1613-6829
DOI:
10.1002/smll.202305258
COBISS.SI-ID:
170529539
Publication date in RUL:
13.02.2024
Views:
342
Downloads:
45
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Title:
Small
Shortened title:
Small
Publisher:
Wiley
ISSN:
1613-6829
COBISS.SI-ID:
512826905
Licences
License:
CC BY-NC-ND 4.0, Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
Link:
http://creativecommons.org/licenses/by-nc-nd/4.0/
Description:
The most restrictive Creative Commons license. This only allows people to download and share the work for no commercial gain and for no other purposes.
Secondary language
Language:
Slovenian
Keywords:
materiali
,
zeoliti
,
kovine
,
cinkovi ioni
,
poroznost
,
katalizatorji
Projects
Funder:
ARRS - Slovenian Research Agency
Project number:
P1-0021
Name:
Nanoporozni materiali
Funder:
ARRS - Slovenian Research Agency
Funding programme:
Young researchers
Funder:
ARRS - Slovenian Research Agency
Project number:
P1-0175
Name:
Napredna anorganska kemija
Funder:
ARRS - Slovenian Research Agency
Project number:
N1-0179
Name:
Odkrivanje reakcij spajanja na podlagi mehanističnih predpostavk
Funder:
ARRS - Slovenian Research Agency
Project number:
P1-0230
Name:
Organska kemija: sinteza, struktura in aplikacija
Funder:
ARRS - Slovenian Research Agency
Project number:
I0-0022
Name:
Mreža raziskovalnih infrastrukturnih centrov Univerze v Ljubljani (MRIC UL)
Funder:
Other - Other funder or multiple funders
Funding programme:
Swedish Research Council
Project number:
2022–06178
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