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Nastavljanje energijske reže perovskitnih FACs sončnih celic
ID PEKLAJ, BLAŽ (Author), ID Jošt, Marko (Mentor) More about this mentor... This link opens in a new window

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Abstract
V diplomskem delu smo raziskali vpliv spreminjanja razmerja cezija (Cs) in formamidinija (FA) na energijsko režo FACs perovskitnih sončnih celic ter kako te spremembe vplivajo na njihove optične ter električne lastnosti. Zmožnost prilagajanja energijske reže pomeni, da je perovskite mogoče prilagoditi za različne aplikacije, kot so različne vrste fotovoltaičnih celic ali svetlečih diod. Izdelali smo 4 kompozicije celic z različnimi deleži Cs in FA. Za vsako kompozicijo smo izdelali 48 celic (8 substratov). Pomerili smo I-U karakteristike celic in izračunali osnovne parametre, kot so napetost odprtih sponk (Voc), gostota toka kratkega stika (Jsc), faktor polnjenja (FF) in učinkovitost pretvorbe moči (PCE). Najboljše celice so dosegle izkoristek nad 19 % in faktor polnjenja nad 75 %. Iz meritev zunanjega kvantnega izkoristka (EQE), fotoluminiscence (PL) in transmisije (T) smo ugotovili, da se z višanjem deleža Cs viša tudi energijska reža perovskita. Za konec smo opravili še sledenje v točki največje moči (MPPT), kjer so vse kompozicije pokazale dobro stabilnost brez degradacije v obdobju 50 minut.

Language:Slovenian
Keywords:sončna celica, energijska reža, perovskit
Work type:Bachelor thesis/paper
Organization:FE - Faculty of Electrical Engineering
Year:2023
PID:20.500.12556/RUL-149719 This link opens in a new window
COBISS.SI-ID:163869443 This link opens in a new window
Publication date in RUL:08.09.2023
Views:235
Downloads:19
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Secondary language

Language:English
Title:Bandgap tuning of perovskite FACs solar cells
Abstract:
In the thesis, we explored the impact of varying the ratio of cesium (Cs) and formamidinium (FA) on the bandgap of FACs perovskite solar cells, and how these changes affect their optical and electrical properties. The ability to tune the bandgap means that perovskites can be adjusted for various applications, such as different types of photovoltaic cells or light-emitting diodes. We fabricated perovskite solar cells with 4 compositions with varying proportions of Cs and FA. For each composition, we created 48 cells (8 substrates). We measured the I-V characteristics of the cells and calculated basic parameters such as open-circuit voltage (Voc), short-circuit current density (Jsc), fill factor (FF), and power conversion efficiency (PCE). The best cells achieved an efficiency of over 19% and a fill factor of over 75%. From measurements of external quantum efficiency (EQE), photoluminescence (PL), and transmission (T), we found that as the proportion of Cs increases, so does the bandgap of the perovskite. Finally, we conducted maximum power point tracking (MPPT), where all the cells showed good stability without degradation during 50 minutes of tracking.

Keywords:solar cell, bandgap, perovskite

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