Strukturna primerjava fenantrolinijevih heksafluoridofosfatov

Golob, Tisa (avtor), Pevec, Andrej (mentor)

V diplomskem delu bom primerjala kristalne strukture petih spojin. Te spojine so sestavljene iz 1,10-fenantrolinijevega kationa ali njegovega derivata in heksafluridofosfatatnega aniona. Spojine, ki jih bom predstavila so: 1,10-fenantrolinijev heksafluoridofosfat, [(phen)H][PF6] (1), 2,9-dimetil-1,10-fenantrolinijev heksafluoridofosfat, [Me2(phen)H][PF6] (2), 9-fenil-1,10-fenantrolinijev heksafluoridofosfat, [Ph(phen)H][PF6] (3), 4,7-difenil-1,10-fenantrolinijev heksafluoridofosfat, [Ph2(phen)H][PF6] (4), 2,9-dimetil-4,7-difenil-1,10-fenantrolinijev heksafluoridofosfat, [Me2Ph2(phen)H][PF6] (5). V diplomski nalogi se bom osredotočila na sintezo posameznih spojin, ter na primerjavo kristalnih struktur spojin, ki so jih dobili z rentgensko strukturno analizo.

• Jezik: Slovenski jezik
• Ključne besede: kristalna struktura, 1, 10-fenantrolin, heksafluoridofosfat, rentgenska strukturna analiza
• Vrsta gradiva: Diplomsko delo/naloga
• Tipologija: 2.11 - Diplomsko delo
• Organizacija: FKKT - Fakulteta za kemijo in kemijsko tehnologijo
• Leto izida: 2023
• PID: 20.500.12556/RUL-149550
• COBISS.SI-ID: 164462595
• Datum objave v RUL: 07.09.2023

Sekundarni jezik

• Jezik: Angleški jezik
• Naslov: Structural comparison of phenanthrolinium hexafluoridophosphates

Izvleček

I will compare the crystal structures of five compounds. These compounds consist of a 1,10-phenanthrolinium cation or its derivative and a hexafluoridphosphate anion. The compounds I will present are: 1,10-phenanthrolinium hexafluoridophosphate, [(phen)H][PF6] (1), 2,9-dimethyl-1,10-phenanthrolinium hexafluoridophosphate, [Me2(phen)H][PF6] (2), 9-phenyl-1,10-phenanthrolinium hexafluoridophosphate, [Ph(phen)H][PF6] (3), 4,7-diphenyl-1,10-phenanthrolinium hexafluoridophosphate, [Ph2(phen)H][PF6] (4), 2,9-dimethyl-4,7-dipheyl-1,10-phenanthrolinium hexafluoridophosphate, [Me2Ph2(phen)H][PF6] (5). I will focus on the synthesis of individual compounds and on the comparison of the crystal structures of the compounds obtained by X-ray diffraction.

• Ključne besede: crystal structure, 1, 10-phenanthroline, hexafluoridophosphate, X-ray diffraction