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Optimizacija ekstrakcije antioksidantov iz PVC
ID Hočevar, Ana (Author), ID Kralj Cigić, Irena (Mentor) More about this mentor... This link opens in a new window

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Abstract
Polivinilklorid je pogosto uporabljan polimer. Za izboljšanje njegovih lastnosti in podaljšanje življenjske dobe so ključni dodatki, saj je v čisti obliki krhek in neprožen. Poleg mehčal in barvil se polimeru dodajajo tudi antioksidanti, ki preprečujejo oksidativno razgradnjo. V diplomskem delu sem optimizirala pripravo vzorca za določanje dveh antioksidantov v PVC; Irganox 1076, ki je primarni antioksidant, in Irgafos 168, ki je sekundarni antioksidant. Vzorce sem raztapljala v mešanici ACN in MQ ter obarjala s THF. Za analizo sem uporabila tekočinski kromatograf z UV-VIS detektorjem. Na koncu sem še določila delež primarnega antioksidanta (Irganox 1076) v vzorcu plastične mape z metodo standardnega dodatka in ugotovila, da je delež en velikostni razred nižji od navedb v literaturi.

Language:Slovenian
Keywords:PVC, antioksidanti, HPLC
Work type:Bachelor thesis/paper
Typology:2.11 - Undergraduate Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2023
PID:20.500.12556/RUL-149510 This link opens in a new window
COBISS.SI-ID:162990851 This link opens in a new window
Publication date in RUL:07.09.2023
Views:464
Downloads:61
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Secondary language

Language:English
Title:Optimization of Antioxidants Extraction from PVC
Abstract:
Polyvinyl chloride is a widely used polymer. Additives are key to improving its properties and extending its lifetime, as it is brittle and inflexible in its pure form. In addition to plasticizers and dyes, antioxidants are added to the polymer to prevent oxidative degradation. In my thesis I optimised the sample preparation for the determination of two antioxidants in PVC; Irganox 1076, which is the primary antioxidant, and Irgafos 168, which is the secondary antioxidant. The samples were dissolved in a mixture of ACN and MQ and precipitated with THF. I used a liquid chromatograph with UV-VIS detector for the analysis. Finally, I determined the proportion of the primary antioxidant (Irganox 1076) in the plastic folder sample by the standard addition method and found that the proportion was one order of magnitude lower than reported in the literature.

Keywords:PVC, antioxidants, HPLC

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