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Vpliv ultrazvočnega soniciranja na zamreževanje TEMPO modificirane nanoceluloze in njenih mešanic
ID Marinič, Matija (Author), ID Ručigaj, Aleš (Mentor) More about this mentor... This link opens in a new window

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Abstract
Hidrogeli so tridimenzionalna polimerna omrežja, ki lahko absorbirajo in zadržijo velike količine vode. So funkcionalni materiali, primerni za uporabo na številnih področjih zaradi svojih dobrih lastnosti in biokompatibilnosti, zlasti za biomedicinske namene. Pri diplomskem delu sem se ukvarjal s pripravo in karakterizacijo hidrogelov pripravljenih iz TEMPO oksidirane nanoceluloze. V okviru eksperimentalnega dela so bile pripravljene različne mešanice hidrogelov iz nanoceluloznih vlaken in skleroglukana. Na podlagi meritev smo hidrogelom določili viskoelastične lastnosti ter spremljali spremembe v strukturi soniciranih in nesoniciranih enokomponentnih raztopin hidrogelov ter mešanic. Sonicirani vzorci tako TEMPO nanoceluze kot vzorci mešanic so se izkazali kot bolj zamreženi z višjimi vrednostmi viskoelastičnih modulov. Sonicirani vzorci so se izkazali za bolj toge v primerjavi z nesonicirani vzorci.

Language:Slovenian
Keywords:TEMPO nanoceluloza, zamreževanje, hidrogel, reologija, ultrazvok
Work type:Bachelor thesis/paper
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2023
PID:20.500.12556/RUL-145173 This link opens in a new window
COBISS.SI-ID:149156867 This link opens in a new window
Publication date in RUL:12.04.2023
Views:672
Downloads:119
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Secondary language

Language:English
Title:Effect of ultrasonic sonication on the crosslinking of TEMPO modified nanocellulose and its blends
Abstract:
Hydrogels are three-dimensional polymer networks that can absorb and retain large amounts of water. They are functional materials suitable for use in several fields due to their good properties and biocompatibility, especially in the biomedical field. In my thesis, I was involved in the preparation and characterization of hydrogels prepared from TEMPO oxidized nanocellulose. As part of the experimental work, various mixtures of hydrogels were prepared from TEMPO nanocellulose fibers and scleroglucan. Based on the measurements, we determined the viscoelastic properties of hydrogels and monitored changes in the structure of sonicated and non-sonicated one-component solutions of hydrogels and their mixtures. Sonicated samples of both TEMPO nanocellulose and mixtures were found to be better cross-linked with higher viscoelastic moduli values. Sonicated samples have proven to be more rigid than non-sonicated samples.

Keywords:TEMPO nanocellulose, crosslinking, hydrogel, rheology, ultrasound

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