A carbonate-templated decanuclear mn nanocage with two different silsesquioxane ligands

Sheng, Kai (avtor), Wang, Ran (avtor), Tang, Xinde (avtor), Jagodič, Marko (avtor), Jagličić, Zvonko (avtor), Pang, Laixue (avtor), Dou, Jian-Min (avtor), Gao, Zhi-Yong (avtor), Feng, Hua-Yu (avtor), Tung, Chen-Ho (avtor), Sun, Di (avtor)

The mild reaction of the preorganized silsesquioxane precursor with Mn(II) acetate under ambient conditions results in a mixed-valent {MnII 6MnIII4} nanocage (SD/Mn10) which is protected by both acyclic trimer [Si3] and cyclic tetramer [Si4]. Serendipitous capture of atmospheric CO2 as a μ5-carbonate anion placed at the center supports the formation of the cluster. The magnetic analysis reveals the strong antiferromagnetic interactions between Mn ions. Moreover, the dropcasting film of SD/Mn10 shows photoelectric activity indicating its great potential as a semiconductor for photoelectric conversion applications.

• Jezik: Angleški jezik
• Ključne besede: Mn(III)-Mn(IV) compound, antiferromagnetism
• Vrsta gradiva: Članek v reviji
• Tipologija: 1.01 - Izvirni znanstveni članek
• Organizacija: FGG - Fakulteta za gradbeništvo in geodezijo
• Leto izida: 2021
• Št. strani: Str. 14866-14871
• Številčenje: Vol. 60, no. 19
• PID: 20.500.12556/RUL-142037
• UDK: 546.71
• ISSN pri članku: 0020-1669
• DOI: 10.1021/acs.inorgchem.1c02190
• COBISS.SI-ID: 124948227
• Datum objave v RUL: 17.10.2022

Gradivo je del revije

• Naslov: Inorganic chemistry
• Skrajšan naslov: Inorg. chem.
• Založnik: American Chemical Society
• ISSN: 0020-1669
• COBISS.SI-ID: 25620480

Sekundarni jezik

• Jezik: Slovenski jezik
• Ključne besede: Mn(III)-Mn(IV) spojina, antiferomagnetizem