In situ prepared polyamide 6/DOPO-derivative nanocomposite for melt-spinning of flame retardant textile filaments

Vasiljević, Jelena (author), Čolović, Marija (author), Jerman, Ivan (author), Simončič, Barbara (author), Demšar, Andrej (author), Samaki, Younes (author), Šobak, Matic (author), Šest, Ervin (author), Golja, Barbara (author), Leskovšek, Mirjam (author), Bukošek, Vili (author), Medved, Jože (author), Barbalini, Marco (author), Malucelli, Giulio (author), Bolka, Silvester (author)

A novel flame retardant polyamide 6 (PA6)/bridged 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO)-derivative (PHED) nanocomposite textile filament yarns were developed. The scalable production approach includes in situ water-catalyzed ring-opening polymerization of ε-caprolactam in the presence of the flame retardant PHED followed by melt-spinning of nanocomposite filament yarns and production of knitted fabrics. The specific chemical structure of the PHED additive enabled its excellent miscibility with molten ε-caprolactam and the uninterrupted polymerization of ε-caprolactam. The produced PA6/PHED nanocomposite was characterized by the preserved molecular structure of the polyamide 6 and uniformly distributed nano-dispersed FR at concentrations of 10 and 15 wt %. The PA6/ PHED nanocomposite structure was successfully preserved after the melt-spinning processing. The PA6 nanocomposite filament yarns at the applied 15 wt %. loading of PHED showed (a) increased thermooxidative stability compared to neat PA6 up to 500 °C, with a 43% higher residue at 500 °C and (b) self-extinguishment of fiber strand and knitted samples within 1 s in standard vertical flame spread tests (ASTM D6413), followed by the significant reduction of the melt-dripping and the melt-drop flammability. Additionally, 1.2 mm-tick PA6/PHED bar samples achieved a V0 rating in UL94 vertical burning test at the applied 10 wt % concentration of PHED. This innovative and scalable approach could pave the way for the production of new-generation nanocomposite PA6 filament yarns with self-extinguishing properties at the macro-scale, which would be highly beneficial for increasing fire safety, whilst maintaining the use of a DOPO derivative at the minimum level.

• Language: English
• Keywords: polyamide 6, DOPO derivative, flame retardant, in situ polymerization, melt-spinning, nanocomposite filament yarns
• Work type: Article
• Typology: 1.01 - Original Scientific Article
• Organization: NTF - Faculty of Natural Sciences and Engineering
• Publication status: Published
• Publication version: Version of Record
• Year: 2019
• Number of pages: Str. 50-59
• Numbering: Vol. 166
• PID: 20.500.12556/RUL-137734
• UDC: 677
• ISSN on article: 0141-3910
• DOI: 10.1016/j.polymdegradstab.2019.05.011
• COBISS.SI-ID: 3602288
• Publication date in RUL: 29.06.2022

Record is a part of a journal

• Title: Polymer degradation and stability
• Shortened title: Polym. degrad. stab.
• Publisher: Elsevier
• ISSN: 0141-3910
• COBISS.SI-ID: 2814212

Licences

• License: CC BY-NC-ND 4.0, Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
• Link: http://creativecommons.org/licenses/by-nc-nd/4.0/
• Description: The most restrictive Creative Commons license. This only allows people to download and share the work for no commercial gain and for no other purposes.

Secondary language

• Language: Slovenian
• Keywords: poliamid 6, DOPO derivati, ognjevarno sredstvo, in situ polimerizacija, predenje, nanokompozitna filamentna preja