KRISTALNE STRUKTURE FENANTROLINIJEVIH HEKSAFLUORIDOMETALATOV

Kužnik, Maša (author), Pevec, Andrej (mentor)

V diplomskem delu sem predstavila dve koordinacijski spojini. To sta spojini [Hphen]2[TiF6] in [Hphen]2[SnF6]. Obema spojinama je skupno, da sta zgrajeni iz ionov: fenantrolinijevega kationa in heksafluoridometalatnega aniona. V anionu je kot centralni kovinski ion titana (1) ali kositra (2) koordiniran s šestimi fluoridnimi ioni kot ligandi. Kation je fenantrolin protoniran na enem od dušikovih atomov. V delu sem se osredotočila na rentgensko strukturno analizo monokristalov in sintezno pot teh dveh spojin.

• Language: Slovenian
• Keywords: kristalna struktura, fenantrolin, heksafluoridotitanat(IV), heksafluoridostanat(IV), rentgenska strukturna analiza
• Work type: Bachelor thesis/paper
• Typology: 2.11 - Undergraduate Thesis
• Organization: FKKT - Faculty of Chemistry and Chemical Technology
• Year: 2022
• PID: 20.500.12556/RUL-135391
• COBISS.SI-ID: 100576515
• Publication date in RUL: 10.03.2022

Secondary language

• Language: English
• Title: CRYSTAL STRUCTURES OF PHENANTHROLINIUM HEXAFLUORIDOMETALLATES

Abstract

In my study I presented two compounds. These are compounds [Hphen]2[TiF6] and [Hphen]2[SnF6]. Both compounds have in common that they consist of ions: phenanthrolinium cation and hexafluoridometallate anion. In the anion is the central metal ion of titanium (1) or tin (2) coordinated with six fluoride ions as ligands. The cation is phenanthroline protonated at one of the nitrogen atoms. In my work I focused on X-ray structure analysis on singlecrystal and on synthesis of these two compounds.

• Keywords: crystal structure, phenanthroline, hexafluoridotitanate(IV), hexafluoridostanate(IV), X-ray structural analysis