KRISTALNE STRUKTURE BIPIRIDINIJEVIH HEKSAFLUORIDOMETALATOV

Šinkovec, Nika (author), Pevec, Andrej (mentor)

V diplomskem delu so predstavljene kristalne strukture štirih koordinacijskih spojin, ki sestojijo iz bipiridinijevega kationa ter heksafluoridometalatnega aniona. Predstavljene so spojine: 2,2'-bipiridinijev heksafluoridotitanat, 4,4'-bipiridinijev heksafluoridotitanat, 4,4'-bipiridinijev heksafluridostanat ter 4,4'-bipiridinijev heksafluoridohafnat. V primeru 2,2'-bipiridinijevega heksafluoridotitanata je protoniran samo en dušikov atom v 2,2'-bipiridinijevem kationu, v ostalih treh spojinah pa sta v 4,4'-bipiridinijevih kationih protonirana oba dušikova atoma. V diplomski nalogi sem se osredotočila na sintezno pot ter rezultate rentgenske strukturne analize posamezne spojine.

• Language: Slovenian
• Keywords: kristalna struktura, bipiridin, heksafluoridometalati, rentgenska strukturna analiza
• Work type: Bachelor thesis/paper
• Typology: 2.11 - Undergraduate Thesis
• Organization: FKKT - Faculty of Chemistry and Chemical Technology
• Year: 2022
• PID: 20.500.12556/RUL-135390
• COBISS.SI-ID: 100573443
• Publication date in RUL: 10.03.2022

ŠINKOVEC, Nika, 2022, KRISTALNE STRUKTURE BIPIRIDINIJEVIH HEKSAFLUORIDOMETALATOV [online]. Bachelor’s thesis. [Accessed 2 April 2025]. Retrieved from: https://repozitorij.uni-lj.si/IzpisGradiva.php?lang=eng&id=135390

Secondary language

• Language: English
• Title: CRYSTAL STRUCTURES OF BIPYRIDINIUM HEXAFLUORIDOMETALLATES

Abstract

The diploma thesis presents the crystal structures of four coordination compounds, consisting of a bipyridinium cation and a hexafluoridometallate anion. The following compounds are presented: 2,2’-bipyridinium hexafluoridotitanate, 4,4’-bipyridinium hexafluoridotitanate, 4,4’-bipyridinium hexafluoridostanate and 4,4’-bipyridinium hexafluoridohafnate. In the case of 2,2’-bipyridinium hexafluoridotitanate, only one nitrogen atom in the 2,2’-bipyridinium cation is protonated, and in the other three compounds both nitrogen atoms are protonated in the 4,4’-bipyridinium cations. In my thesis, I focused on the synthesis pathway and the results of X-ray structural analysis of each compound.

• Keywords: crystal structure, bipyridine, hexafluoridometallates, X-ray crystallography