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Priprava mikrokapsul z različnimi površinskimi naboji
ID Vrhunec, Enej (Author), ID Podgornik, Aleš (Mentor) More about this mentor... This link opens in a new window

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Abstract
Mikroinkapsulacija je priznana kot učinkovita metoda za zaščito različnih vrst aktivnih snovi na različnih področjih uporabe, kot so medicina, agrokemija, industrijske kemija in nedavno še tekstil. Ena od bolj uporabljenih tehnik je inkapsulacija z medfazno polimerizacijo, pri kateri pride do reakcije in s tem tvorjenjem stene na fazni meji med vodno in organsko fazo. Jedrni material je lahko tekoča trdna ali dispergirana snov, ki se emulgira znotraj kontinuirne faze, dokler se ne doseže želena velikost emulzije. Za tem sledi dodatek monomerov in začetek polimerizacije na fazni meji. Pomembna lastnost mikroinkapsul je njihov površinski naboj, s katerim se lahko mikrokapsule bolje oprimejo tarčne površine. V magistrskem delu smo z različnimi dodatki uspeli pridobiti mikrokapsule s pozitivnim in negativnim nabojem kot tudi mikrokapsule brez naboja, ki smo jim določili zeta potencial. Za karakterizacijo vzorcev smo izvedli še analizo na optičnem mikroskopu, gravimetrično analizo in meritev porazdelitve velikosti delcev. Za konec smo izvedli tudi impregnacijo vzorcev na tekstilne materiale, na katerih smo z metodo določanja intenzivnosti vonja preverjali sposobnost oprijema mikrokapsul z različnimi naboji.

Language:Slovenian
Keywords:mikrokapsule, poliuretan-sečnina, površinski naboj
Work type:Master's thesis/paper
Typology:2.09 - Master's Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2022
PID:20.500.12556/RUL-135071 This link opens in a new window
COBISS.SI-ID:98749443 This link opens in a new window
Publication date in RUL:21.02.2022
Views:650
Downloads:38
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Secondary language

Language:English
Title:Preparation of microcapsules with different surface charges
Abstract:
Microencapsulation is recognized as an effective method for the protection of various types of active substances in various fields of application, such as medicine, agrochemistry, industrial chemistry and, more recently, textiles. One of the most widely used techniques is encapsulation by interfacial polymerization, in which a reaction occurs and thus a wall is formed at the interface between the aqueous and organic phase. The core material can be a liquid solid or dispersed substance that is emulsified within a continuous phase until the desired emulsion size is reached. This is followed by the addition of monomers and the start of polymerization at the interface. An important feature of microcapsules is their surface charge, which allows them to adhere better to the target surface. In my master's thesis, I was able to obtain microcapsules with positive and negative charge, as well as microcapsules without charge, with various additives. Charge was determined with the zeta potential measurement. To characterize the samples, I performed analysis on an optical microscope, gravimetric analysis, and measurement of particle size distribution. Finally, I impregnated the samples on textile materials, for which I used the method of odor intensity determination to analyse the adhesion of microcapsules with different charges.

Keywords:microcapsules, polyurethane-urea, surface charge

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