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Uporaba koloidnih sistemov pri postopkih čiščenja predmetov kulturne dediščine s poudarkom na poli(vinil alkoholnih) hidrogelih
ID Bremec Kodelja, Lara (Author), ID Lukšič, Miha (Mentor) More about this mentor... This link opens in a new window

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Abstract
Postopki čiščenja predmetov kulturne dediščine se z leti razvijajo. Nekoč so bila poglavitno uporabljena organska topila, ki so okolju in človeku škodljiva. Sedaj je pri konservacijsko-restavracijskih postopkih najbolj razširjena raba koloidnih sistemov, ki minimizirajo porabo toksičnih topil in zmanjšajo nevarnost poškodb čiščenih predmetov. Primer koloidnih sistemov so geli, ki jih sestavljata vsaj dve komponenti: polimer in tekočina, ki zapolnjuje polimerno mrežo. Ta tekočina je lahko navadno topilo ali pa mikroemulzija, ki je stabilna koloidna disperzija dveh tekočin, ki se med seboj ne mešata in je ena razpršena v drugi. Tip čistilnega sredstva je določen na podlagi lastnosti čiščenega predmeta. Pomembno je, da slednji ostane nepoškodovan in da na njegovi površini ne ostajajo delci gela oz. druge vrste čistila. Posebna vrsta gelov so poli(vinil) alkohol hidrogeli. Njihove lastnosti so prilagojene posameznemu artefaktu z različnimi načini sinteze, ki so lahko sušenje v kalupu ali zamrzovanje in odtajanje v enem ali več ciklih. Poleg načina sinteze, ki vpliva na zamrežitev gela in s tem na njegove visko-elastične lastnosti in sproščanje tekočine, lahko na te lastnosti vplivamo tudi z dodatkom poli(vinil) pirolidona, ki hidrogelu poveča poroznost.

Language:Slovenian
Keywords:koloidni sistemi, mikroemulzije, PVA hidrogeli, kulturna dediščina
Work type:Bachelor thesis/paper
Typology:2.11 - Undergraduate Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2021
PID:20.500.12556/RUL-132255 This link opens in a new window
COBISS.SI-ID:88816131 This link opens in a new window
Publication date in RUL:19.10.2021
Views:950
Downloads:99
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Secondary language

Language:English
Title:Use of colloidal systems in procedures of cleaning cultural heritage objects with the focus on poly(vinyl alcohol) hydrogels
Abstract:
The procedures of cleaning cultural heritage objects are evolving each year. In the past, the primary method of cleaning involved the use of organic solvents, which are harmful to the environment and people. Presently the use of colloidal systems is the main method in the conservation-restoration procedures. These systems minimize the usage of toxic solvents and decrease the chance of damaging the objects we clean. An example of colloidal systems are gels. These are systems of at least two components: a polymer and a fluid that fills the polymer mesh. The fluid can either be a solvent or a microemulsion, which is a stable colloid dispersion of two fluids that don’t mix, where one is dispersed in the other. Gels, solvents and microemulsion are chosen specifically for each cleaned object. It is crucial that the object stays undamaged and that no residues of gel remain on its surface. A special type of gel is poly(vinyl) alcohol hydrogel. Its characteristics can be modified by different methods of synthesis, which are cast-drying and freeze-thawing by one or more cycles. Besides different synthesis methods, the addition of poly(vinyl) pyrrolidone also affects viscoelastic characteristics and the release of fluid. Poly(vinyl) pyrrolidone increases the porosity of the hydrogel.

Keywords:colloidal systems, microemulsions, PVA hydrogels, cultural heritage

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