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Monitoring tal saniranega otroškega igrišča v MO Ljubljana
ID Bavdek, Blaž (Author), ID Zupan, Marko (Mentor) More about this mentor... This link opens in a new window

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Abstract
V magistrski nalogi smo analizirali tla saniranega otroškega igrišča v vrtcu Hiša pri ladji v MO Ljubljana. V letu 2015 je bila izvedena sanacija z zamenjavo zgornjega sloja tal zaradi povečane vsebnosti svinca (Pb). Koncentracije Pb v tleh na globini 0-10 cm so bile od 34,8 do 2793 mg/kg in na globini 10-20 cm od 32,4 do 6616 mg/kg tal. Po odstranitvi onesnažene zemljine do globine 50 cm je bil najprej vgrajen sloj gramoza (tampon), ki je bil prekrit z novo zemljino, v kateri je bila koncentracija Pb 51,4 mg/kg, kadmija 0,41 mg/kg, arzena 9,3 mg/kg in cinka 140 mg/kg. Zanimalo nas je, če so se koncentracije Pb in drugih analiziranih težkih kovin po petih in pol letih povečale do te mere, da tla otroškega igrišča ponovno predstavljajo zdravstveno tveganje za otroke. Koncentracija Pb v letu 2021 je bila na vzorčni globini 0-10 cm med 39,3 in 60,6 mg/kg, na vzorčni globini 10-20 cm pa med 40,9 in 51,5 mg/kg tal. Na vzorčni globini 30-40 cm smo večinoma vzorčili tamponski sloj nasutja karbonatnega grušča iz leta 2015, ki preprečuje ponovno kontaminacijo zgornjih plasti iz spodnjih ne saniranih tal. Z analizami Pb smo potrdili, da so tla na vzorčni globini 60-70 cm še vedno onesnažena. Analize svinca smo opravili z ne destruktivno metodo rentgenske fluorescenčne spektrometrije (XRF) in v združenih vzorcih tal tudi po metodi kislinskega razklopa z zlatotopko. Biodosegljivost Pb smo določali z in vitro metodo, ki jo je določila U.S. EPA. Absolutna biodostopnost je bila med 27,6 in 33,8 %. Z modelom IEUBK, smo izračunali pričakovano koncentracijo Pb v krvi otrok, ki je bila pod 10 µg/dl. Izvedli smo tudi osnovne pedološke analize: vsebnost karbonatov, kislost tal, vsebnost organske snovi ter založenost tal s fosforjem in kalijem na osnovi katerih smo podali priporočila za vzdrževanje tal otroškega igrišča.

Language:Slovenian
Keywords:onesnaženost tal, otroško igrišče, sanacija, monitoring
Work type:Master's thesis/paper
Typology:2.09 - Master's Thesis
Organization:BF - Biotechnical Faculty
Place of publishing:Ljubljana
Publisher:[B. Bavdek]
Year:2021
PID:20.500.12556/RUL-128143 This link opens in a new window
UDC:631.453:502.175:712.256(043.2)
COBISS.SI-ID:69150467 This link opens in a new window
Publication date in RUL:04.07.2021
Views:940
Downloads:117
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Secondary language

Language:English
Title:Soil monitoring of remediated children's playgroud in municipality of Ljubljana
Abstract:
We investigated the soils of the remediated children’s playground in the kindergarten Hiša pri ladji in the municipality of Ljubljana. The remediation was carried out in 2015 by replacing of a 50 cm topsoil layer due to the increased lead (Pb) content. Pb content ranged from 24,8 to 2793 mg/kg in topsoil 0-10 cm, and from 32,4 to 6616 mg/kg in soil layer 10-20 cm. After removing the contaminated soils, a layer of gravel was inserted and then covered with new soils with Pb content 51,4 mg/kg, cadmium content 0,41 mg/kg, arsenic content 9,3 mg/kg and zinc content 140 mg/kg. The aim of this thesis was to check whether the concentrations of Pb and other analysed heavy metals increased after five and a half years and represent the health risk to the children. In the year 2021 Pb content ranged from 39,3 to 60,6 mg/kg in the sampling depth 0-10 cm, and from 40,9 to 51,5 mg/kg in the sampling depth 10-20 cm. Samples from the depth 30-40 cm represents the carbonate gravel, which was inserted in 2015 and has a task to prevent recontamination of upper layers from lower layers of contaminated soils. Pb content from the sampling depth 60-70 cm confirmed that soils are still contaminated. Pb analyses were performed by the non-destructive method of X-ray fluorescence spectrometry (XRF) and also with aqua regia extraction method. Pb bioavailability was determined by the in vitro bioaccessibility assay developed by U.S. EPA. Absolute bioavailability of Pb ranged from 27,6 to 33,8 %. Using IEUBK model, we calculated the expected Pb concentration in the blood of children, which was below 10 µg/dl. We carried out also soil properties like carbonate content, soil acidity, soil organic matter and available phosphorus and potassium for topsoil management recommendations.

Keywords:soil contamination, children's playground, remediation, monitoring

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