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The Effect of pH on Phosphate Solubility in soils
ID Mrak, Klara (Author), ID Wenzel, Walter W. (Mentor) More about this mentor... This link opens in a new window, ID Suhadolc, Marjetka (Comentor)

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Abstract
When proposing solutions for a more sustainable use of phosphorus (P) in agriculture, we should consider the complex interactions of biotic and abiotic factors that ultimately affect P mobility. Soil pH is a master variable of P-solubility. Published laboratory studies suggest minimum solubility of soil phosphorus (P) in the pH range, which is traditionally the target of agricultural interventions, such as lime applications. In this thesis, low and high P field-collected soils, as well P-spiked soils, were used to determine the response of P solubility to changes in pH. We changed the pH by adding base or acid to aqueous soil slurries and sodium nitrate was used as background electrolyte. In the slurries we determined P photometrically and the concentrations of P, Ca, Al and Fe and by inductively coupled plasma optical emission spectrometry (ICP-OES). We show that P solubility in low-P soils is likely controlled by desorption and, contrary to textbook information, has a solubility minimum near pH 6-7. In some high P (fertilized) soils, this pattern is likely altered by the dissolution of Ca-P minerals. In terms of methodology, we find that the colorimetrically measured P-concentration is lower, which we attribute mainly to the fact that P adsorbed on colloidal particles is not measured with this method. Further research is still needed to understand the relationship between basic soil properties, like soil pH in relation to phosphate solubility better. This will enable science to make accurate predictions and propose improved nutrient management practices to pass on to regulatory bodies, the industry and farmers.

Language:English
Keywords:Phosphorus, phosphate solubility, soil pH, liming, fertilizer
Work type:Master's thesis/paper
Typology:2.09 - Master's Thesis
Organization:BF - Biotechnical Faculty
Publisher:[K. Mrak]
Year:2021
PID:20.500.12556/RUL-124577 This link opens in a new window
UDC:631.415.2:631.416:549.755:544.351.3(043.2)
COBISS.SI-ID:59517443 This link opens in a new window
Publication date in RUL:04.02.2021
Views:981
Downloads:120
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Secondary language

Language:Slovenian
Title:Vpliv pH na topnost fosfata v tleh
Abstract:
Pri predlogih ukrepov za bolj trajnostno uporabo fosforja (P) v kmetijstvu, je potrebno upoštevati zapletene interakcije biotskih in abiotskih dejavnikov, ki vplivajo na dinamiko P v tleh. Vrednost pH tal je glavna kontrolna spremenljivka topnosti P. Objavljene laboratorijske študije pokažejo minimalno topnost fosforja v tleh v območju pH, ki je tradicionalno tarča kmetijskih posegov, kot je apnjenje. V magistrski nalogi smo v vzorcih tal iz poljskih poskusov z majhnimi in velikimi vsebnostmi P, ter v tleh z dodanim P, določali odziv topnosti P na spremembo pH v suspenziji tal z dodajanjem kisline oz. baze. Kot osnovni elektrolit smo uporabili natrijev nitrat. V suspenzijah smo fotometrično določili vsebnost P in z atomsko emisijsko spektroskopijo z induktivno sklopljeno plazmo vsebnosti P, Ca, Al in Fe. Pokazali smo, da je topnost P v tleh z majhno vsebnostjo P verjetno nadzorovana z desorpcijo, in dosega, v nasprotju s pogostimi navedbami, najmanjše vrednosti okrog pH 6-7. V nekaterih s P bogatih tleh (gnojenih) je vzorec topnosti spremenjen, verjetno zaradi raztapljanja Ca-P mineralov. V metodološkem smislu ugotavljamo, da je kolorimetrično izmerjena koncentracija P manjša, kar pripisujemo predvsem dejstvu, da s to metodo hkrati s preostalim P ne izmerimo P, ki je adsorptivno vezan na koloidne delce. Za razumevanje razmerja med osnovnimi lastnostmi tal, kot je pH tal v odnosu s topnostjo fosfatov, so potrebne nadaljnje raziskave, ki bodo znanosti omogočile natančnejše napovedi o agroekologiji fosfata. Tovrstna dognanja so potrebna za izboljšano prakso upravljanja s hranili, prenesti pa se morajo iz znanosti na regulativne organe, industrijo in kmete.

Keywords:Fosfor, topnost fosfata, pH tal, apnjenje, gnojenje

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