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Vpliv sestave urea-formaldehidnega lepila na njegove reološke in dielektrične lastnosti med procesom utrjevanja : magistrska naloga
ID Cilenšek, Boris (Author), ID Šernek, Milan (Mentor) More about this mentor... This link opens in a new window, ID Petrič, Marko (Reviewer)

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Abstract
Proučevali smo vpliv sestave urea-formaldehidne lepilne mešanice na reološke in dielektrične lastnosti med utrjevanjem. Vzorci lepila so se med seboj razlikovali v molarnem razmerju med ureo in formaldehidom; eden od vzorcev pa je vseboval dodatek melamina. Lepilne mešanice so bile že predhodno pripravljene, pred poskusom jim je bilo treba dodati le še katalizator. Testiranja smo izvajali z reometrom ARES-G2, ki je bil povezan z računalnikom in LCR-metrom. Tako nam je bilo omogočeno, da smo hkrati spremljali reološke in dielektrične lastnosti lepila med procesom utrjevanja. Pripravljeno lepilno mešanico smo nanesli na aluminijaste diske, jih približali na želeno razdaljo in sprožili meritev. Temperatura segrevanja večine vzorcev je bila od 30 °C do 85 °C. Iz podatkov meritev smo za posamezne vzorce izračunali stopnjo utrjenosti. Ugotovili smo, da molarno razmerje med ureo in formaldehidom vpliva na reološke in dielektrične lastnosti, prav tako kot dodatek melamina ali moke. Pri večjih količinah dodanega katalizatorja smo beležili višje vrednosti obeh komponent strižnega modula in prevodnosti, same reakcije utrjevanja pa so potekale hitreje. Opazili smo korelacijo med rezultati obeh metod in sicer na osnovi tipičnih točk konverzije lepila, kot sta točka želiranja in zamreženja. Ugotovili smo tudi precejšno podobnost med izračuni stopnje utrjenosti iz elastičnega strižnega modula in prevodnosti, zlasti pri večjem dodatku katalizatorja.

Language:Slovenian
Keywords:dielektrične lastnosti, prevodnost, reologija, strižni modul, urea-formaldehidno lepilo, utrjevanje
Work type:Master's thesis/paper
Typology:2.09 - Master's Thesis
Organization:BF - Biotechnical Faculty
Place of publishing:Ljubljana
Publisher:[B. Cilenšek]
Year:2013
Number of pages:XII, 50 f.
PID:20.500.12556/RUL-122421 This link opens in a new window
UDC:630*824.843
COBISS.SI-ID:2169481 This link opens in a new window
Publication date in RUL:10.12.2020
Views:973
Downloads:87
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Secondary language

Language:English
Title:Effect of composition of urea-formaldehyde adhesive on its rheological and dielectric properties during curig process : M. Sc. thesis
Abstract:
Effect of urea-formaldehyde adhesive composition on rheological and dielectric properties during curing was examined. The main difference among adhesive samples was different molar ratio between urea and formaldehyde. One sample also contained melamine. Adhesive mixtures were pre-prepared, we just added a catalyst before testing. Tests were made using rheometre ARES-G2, connected to a computer and LCR metre. In this way we gained ability to analyze rheological and dielectric properties together during curing. A sample of a prepared adhesive mixture was applied on aluminium discs. Then we approached discs on a required distance and launched measurement. The heating temperature was set from 30 °C to 85 °C for most of the samples. From the test data, the degree of curing was calculated for each sample. We found out that the molar ratio between urea and formaldehyde affected rheological and dielectric properties, just as an addition of melamine and flour. When the quantity of the catalyst was higher, higher values for both components of shear modulus and conductivity were recorded, and also the curing reaction was faster. On the basis of typical points of adhesive conversion, as gel and vitrification points, a correlation between the results of both methods was detected..Significant similarity among the results of degree of curing calculated out of storage modulus and conductivity was discovered as well.

Keywords:dielectric properties, conductivity, rheology, shear modulus, urea-formaldehyde adhesive, curing

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