Analiza sinteznih postopkov in struktur srebrovih koordinacijskih spojin z imidazolidin-2-tioni in načrtovanje sintez analognih srebrovih koordinacijskih spojin s 1,2,4-triazolidin-3-tioni.

BUNARKIĆ, MARKO (author), Kljun, Jakob (mentor)

Namen diplomske naloge je bil preučiti znane sintezne protokole srebrovih enojedrnih in dvojedrnih koordinacijskih spojin z imidazolidin-2-tioni v razmerjih 1:2, 1:3, 1:4, 2:4 in 2:6 ter preučiti ternarne komplekse z imidazolidin-2-tioni in trifenilfosfinom ali fenantrolinom. V okviru diplomske naloge sem analiziral tudi kristalne strukture nekaterih kompleksov in nato predlagal sintezne postopke za pripravo analognih spojin s 1,2,4-triazolidin-3-tioni.

• Language: Slovenian
• Keywords: srebro, imidazolidin-2-tion, 1, 2, 4-triazolidin-3-tion
• Work type: Bachelor thesis/paper
• Typology: 2.11 - Undergraduate Thesis
• Organization: FKKT - Faculty of Chemistry and Chemical Technology
• Year: 2020
• PID: 20.500.12556/RUL-119668
• COBISS.SI-ID: 30771971
• Publication date in RUL: 10.09.2020

Secondary language

• Language: English
• Title: Analysis of synthetic procedures and structures of silver coordination compounds with imidazolidine-2-thione ligands and the design of analog silver coordination compounds with 1,2,4-triazolidine-3-thiones

Abstract

The purpose of my thesis was to study the known synthetic protocols of silver mononuclear and dinuclear coordination compounds with imidazolidine-2-thions in the ratios 1:2, 1:3, 1:4, 2:4, 2:6 and to study ternary complexes with imidazolidine-2-thions and triphenylphosphine or phenanthroline. Also, crystal structures of some complexes were analysed. Analog compounds with 1,2,4-triazolidine-3-thiones were designed.

• Keywords: silver, imidazolidine-2-thion, 1, 2, 4-triazolidine-3-thion