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Priprava NCN kleščastih ligandov
ID Bezlaj, David (Author), ID Cerkovnik, Janez (Mentor) More about this mentor... This link opens in a new window

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Abstract
Vsebina diplomskega dela opisuje kleščaste ligande. Največ poudarka je na NCN kleščastih ligandih, vendar so omenjeni tudi drugi. Prav tako je opisana struktura kleščastih ligandov in kako jih lahko modificiramo, da spremenimo njihove lastnosti. Opisane so tudi vrste reakciji, pri katerih se kompleksi teh ligandov uporabljajo kot katalizatorji. Poleg zmožnosti katalize so naštete še nekatere druge možne uporabe teh kompleksov. Nazadnje so opisane še tri možne sintezne poti za 1,3-bis(2-piridil)benzen NCN kleščasti ligand, ki sem ga želel tudi sintetizirati, vendar zaradi posebnih okoliščin eksperimentalnega dela nisem opravljal. Opisan je tudi način priprave kompleksa tega liganda s kovinami in kje so ti kompleksi našli svojo uporabo. V zaključku so opisani tudi drugi, manj pogosti kleščasti ligandi, kot so PCP in SCS kleščasti ligandi.

Language:Slovenian
Keywords:NCN kleščasti ligandi, kleščasti kovinski kompleksi, katalizator
Work type:Bachelor thesis/paper
Typology:2.11 - Undergraduate Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Technology
Year:2020
PID:20.500.12556/RUL-119524 This link opens in a new window
COBISS.SI-ID:28493827 This link opens in a new window
Publication date in RUL:09.09.2020
Views:1307
Downloads:122
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Secondary language

Language:English
Title:Preparation of NCN pincer ligands
Abstract:
Pincer ligands are presented in this work. The emphasis is on NCN pincer ligands, but others are also mentioned. The structure of the pincer ligands and how they can be modified to change their properties are also described. Reactions in which metal complexes of these ligands are used as catalysts are also discussed. In addition to their ability to catalyze, some other possibilities for the use of these complexes are listed. Finally, three synthetic pathways for 1,3-bis(2-pyridyl)benzene NCN pincer ligand, which I also intend to synthesize, are described, together with the preparation of metal complexes with this ligand and their potential application. In conclusion, some other pincer ligands, which are slightly different and not as common as PCP and SCS ligands, are described.

Keywords:NCN pincer ligands, metal pincer complexes, catalyst

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