Priprava kleščastih kompleksov

PAVLIN, UROŠ (author), Cerkovnik, Janez (mentor)

V diplomski nalogi sem se osredotočil na pripravo kleščastih kompleksov tipa NCN-M (M = Pt, Pd, Ni). Najprej sem pripravil kleščasti NCN ligand, nato pa je sledila sinteza kompleksa s Pt, Pd in Ni kot kovino. Uspešno sem pripravil kleščaste komplekse s platino in paladijem, vendar mi kleščastega kompleksa s paladijem ni uspelo izolirati. Nastale produkte sem analiziral z 1H NMR spektroskopijo in plinsko kromatografijo, sklopljeno z masnim detektorjem (GC-MS).

• Language: Slovenian
• Keywords: Ključne besede: PCP in CNC kleščasti ligandi, kleščasti kompleksi s platino, paladijem in nikljem, koordinacijske spojine
• Work type: Bachelor thesis/paper
• Typology: 2.11 - Undergraduate Thesis
• Organization: FKKT - Faculty of Chemistry and Chemical Technology
• Year: 2020
• PID: 20.500.12556/RUL-116764
• COBISS.SI-ID: 19038467
• Publication date in RUL: 09.06.2020

Secondary language

• Language: English
• Title: Preparation of pincer complexes

Abstract

In this work the preparation of NCN-M (M = Pt, Pd, Ni) pincer ligands and pincer complexes is described. First, NCN pincer ligand was prepared, followed by the synthesis of the complexes with Pt, Pd, and Ni metal. Complexes of platinum and palladium were sucessfully synthesized, however palladium pincer complex was not isolated. Products were analyzed with 1H NMR sprectroscopy and GC-MS chromatography.

• Keywords: Keywords: PCP and NCN pincer ligands, platinum, palladium, and nickel pincer complexes, coordination compounds