Fluoridooksidovanadati nekaterih nukleinskih baz

Stražišar, Tina (avtor), Pevec, Andrej (mentor)

V okviru diplomskega dela sem sintetizirala dve novi spojini s fluoridooksidovanadatnimi anioni in nukleinskimi bazami kot kationi. Kot nukleinske baze sem uporabila adenin, gvanin in uracil. Soli so nastale pri reakciji med vanadijevim(V) oksidom, fluorovodikovo kislino in ustrezno nukleinsko bazo. Fluorovodikova kislina reagira s steklom, zato sem morala pri sintezah uporabljati plastični inventar. Nastale kristale sem karakterizirala z infrardečo spektroskopijo, nuklearno magnetno resonančno spektroskopijo, elementno CHN analizo in rentgensko strukturno analizo.

• Jezik: Slovenski jezik
• Ključne besede: fluoridooksidovanadati(V), sinteza, IR spektroskopija, NMR spektroskopija.
• Vrsta gradiva: Diplomsko delo/naloga
• Tipologija: 2.11 - Diplomsko delo
• Organizacija: FKKT - Fakulteta za kemijo in kemijsko tehnologijo
• Leto izida: 2019
• PID: 20.500.12556/RUL-109298
• COBISS.SI-ID: 1538301891
• Datum objave v RUL: 29.08.2019

Sekundarni jezik

• Jezik: Angleški jezik

Izvleček

Two new compounds containing fluoridooxidovanadate anion and nucleobases as cations have been synthesized. As nucleobases I used adenine, guanine and uracil. Salts were obtained by the reaction of vanadium(V) oxide, hydrofluoric acid and an appropriate nucleobase. Due to the reaction of hydrofluoric acid with glass I had to use a plastic labware for synthesis. The crystals which were obtained as products were characterized by infrared spectroscopy, nuclear magnetic resonance spectroscopy, elemental CHN analysis and X-ray structural analysis.

• Ključne besede: fluoridooksidovanadates(V), synthesis, IR spectroscopy, NMR spectroscopy.