20.500.12556/RUL-85993 Sinteza in karakterizacija koordinacijskih spojin cinka(II) z anionom kinaldinske kisline in piridinskimi ligandi. Synteses and characterizaton of coordination compounds of zinc(II) with quinaldinate and pyridine ligands. V svojem diplomskem delu sem pripravila in karakterizirala različne koordinacijske spojine cinka(II) s kinaldinatom. Najprej sem iz cinkovega(II) acetata pripravila spojino s koordiniranim kinaldinatom in metanolom, [Zn(kinal)2(MeOH)2]. To je bila tudi moja izhodna spojina. Koordinirani metanol sem poskušala v različnih topilih zamenjati s 4-hidroksimetilpiridinom, piridinom, 3-hidroksipiridinom ali piridin N-oksidom. Reakciji s prvima dvema ligandoma (L= 4-hmpy, py) sta uspeli: [Zn(kinal)2(MeOH)2] + 2L  [Zn(kinal)2L2] + 2MeOH Pri reakcijah s 3-hidroksipiridinom ali piridin N-oksidom pa nastane produkt s koordinirano vodo, [Zn(kinal)2(H2O)]. A series of zinc(II) complexes with quinaldinate were prepared and structurally characterized. A starting material, [Zn(kinal)2(MeOH)2], was prepared upon the reaction of zinc(II) acetate with quinaldic acid. The main aim was to replace the coordinated methanol with 4-hydroxymethylpyridine, pyridine, 3-hydroxypyridine or pyridine N-oxide. Reactions with the first two ligands (L=4-hmpy, py) were met with success: [Zn(kinal)2(MeOH)2] + 2L  [Zn(kinal)2L2] + 2MeOH Reactions with 3-hydroxypyridine or pyridine N-oxide resulted in a complex with coordinated water, [Zn(kinal)2(H2O)]. cinkov(II) acetat zinc(II) acetate true false false Slovenski jezik Angleški jezik Diplomsko delo/naloga 2016-10-04 02:42:19 2017-09-19 17:28:22 2025-04-17 04:52:34 0000-00-00 00:00:00 2016 0 0 0000-00-00 NiDoloceno NiDoloceno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 11203401 Brzuhalski_Valentina.pdf Brzuhalski_Valentina.pdf 1 2CAE3EBB91086464D2C39E6AD9FB1087 ff9743aafb51910ac5bef6d69bff8ff44b18a9cbbcbb1f1eb55037fd2cc93a56 e2fee3d4-1aab-11f0-b232-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=204882 Pedagoška fakulteta 0 0 0