20.500.12556/RUL-190029 Effect of a binary solvent mixture of methyl and ethyl myristate on colour hysteresis in a microencapsulated leuco dye thermochromic system Microencapsulated reversible thermochromic systems based on leuco dyes often exhibit broad colour hysteresis between the coloured and decoloured states, which can reduce the reliability of printed temperature indicators. In this study, we investigated whether a binary fatty acid ester solvent mixture near the eutectic composition could narrow this hysteresis and mitigate the effect of microencapsulation on solvent crystallisation. Methyl myristate (MeM) and ethyl myristate (EtM) were used as model ester solvents, while crystal violet lactone and benzyl 4-hydroxybenzoate served as the leuco dye and developer, respectively. Differential scanning calorimetry of bulk MeM/EtM mixtures identified the mixture containing 40 mol% MeM as exhibiting the clearest eutectic-like behaviour. This mixture was therefore selected and compared with the corresponding pure ester systems before and after microencapsulation in a melamine-formaldehyde shell. Scanning electron microscopy and laser diffraction confirmed the formation of spherical, well-separated microcapsules with comparable bimodal particle size distributions. All prepared systems showed reversible thermochromic behaviour. The 40 mol% MeM system exhibited the narrowest colour hysteresis in both bulk and microencapsulated forms. Upon microencapsulation, the downward shift in crystallisation onset temperature was less pronounced for the binary thermochromic system than for the corresponding pure ester systems, and a similarly smaller shift was observed for the onset of colouration. Comparison of thermal and colourimetric measurements showed that colouration was closely associated with solvent crystallisation, whereas decolouration began below the DSC melting onset. These results indicate that, in the investigated MeM/EtM system, a binary ester solvent mixture exhibiting eutectic-like behaviour can limit the confinement-induced shift in crystallisation and colouration towards lower temperatures, resulting in a narrower colour hysteresis after microencapsulation. leuco dye thermochromism colour hysteresis microencapsulation fatty acid esters temperature indicator leuko barvilo termokromizem barvna histereza mikroenkapsulacija estri maščobnih kislin temperaturni indikator true false true Angleški jezik Slovenski jezik Članek v reviji 2026-10-21 04:19:04 2026-10-23 06:20:35 2026-10-24 04:36:49 0000-00-00 00:00:00 2027 0 0 15 str. pt. 2, art. 114297 Vol. 257 2027 0000-00-00 Zaloznikova Objavljeno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 535.6 0143-7208 10.1016/j.dyepig.2026.114297 301665795 1-s2.0-S0143720826007497-main.pdf 1-s2.0-S0143720826007497-main.pdf 1 FD84638938972FCCA8EC236CCA00EFB2 e5992f999e581597769ea7ff25d1bbd9a462e7cea217cf3544c3459bd2f76a30 f8460f5a-ce98-11f1-aea2-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=251180 https://www.sciencedirect.com/science/article/pii/S0143720826007497 1 9a3a1ed2-ccf5-11f1-8bc5-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=251017 Naravoslovnotehniška fakulteta 0 0 0