20.500.12556/RUL-188113 Lignin-derived carbon quantum dot–sensitized TiO$_2$ for enhanced visible-light photocatalytic simultaneous degradation of pharmaceuticals Titanium dioxide (TiO$_2$) photocatalysis is a promising advanced oxidation method for water treatment, but its reliance on UV irradiation limits practical solar-driven applications. This study addresses this limitation by synthesizing lignin-based carbon quantum dots (L–CQDs) from kraft lignin and combining them with anatase TiO$_2$ to create a visible-light-active hybrid photocatalyst. L–CQDs/TiO$_2$ composites with 1–4 wt.% L–CQD loadings were prepared, thoroughly characterized, and evaluated for photocatalytic performance under simulated visible light (400–700 nm). The optimized 3 wt.% L–CQDs/TiO$_2$ hybrid achieved simultaneous degradation of sulfamethoxazole (SMX) and ibuprofen (IBU) with removal efficiencies of 98.6% and 79.7%, respectively, after 90 min – representing 118-fold and 5-fold increases in pseudo-first-order rate constants compared to bare TiO2. Radical scavenging experiments revealed a dual degradation mechanism: SMX was degraded mainly by superoxide radicals in the bulk solution, while IBU was degraded at the photocatalyst surface via photogenerated holes, with hydroxyl radicals playing a negligible role. Density functional theory calculations of frontier molecular orbital energies supported this mechanistic distinction. Matrix effects in tap water selectively suppressed IBU degradation due to competing hole consumption by CO$_3$$^{2-}$ and Cl$^-$, while SMX degradation remained unaffected. These findings demonstrate that L–CQDs act as a sustainable photosensitizer, shifting TiO$_2$ activity into the visible range through a charge-transfer mechanism rather than direct band gap modification, enabling efficient multi-pollutant removal under solar-relevant irradiation. lignin carbon quantum dots titanium dioxide photocatalysis water pollution sulfamethoxazole ibuprofen ogljikove kvantne pike iz lignina titanov dioksid fotokataliza onesnaževanje vode sulfametoksazol ibuprofen true false true Angleški jezik Slovenski jezik Članek v reviji 2026-09-18 11:27:13 2026-09-18 11:27:15 2026-09-19 04:30:09 0000-00-00 00:00:00 2026 0 0 13 str. Vol. 28, art. 101465 Nov. 2026 0000-00-00 Zaloznikova Objavljeno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 546.82-31:544.526.5 2666-8211 10.1016/j.ceja.2026.101465 291107331 RAZ_Ullah_Azmat_2026.pdf RAZ_Ullah_Azmat_2026.pdf 1 4C040BB7ACF0870ED7672E6A87C9DA96 5033d7ad1a2dcc2314de6f044163f46b843c988a0462bb03436aeb4e65ae14ad beee5b7c-b343-11f1-8bc5-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=248125 https://www.sciencedirect.com/science/article/pii/S2666821126004321 1 183fd442-b343-11f1-8bc5-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=248124 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0