20.500.12556/RUL-187637 Razvoj mehanizma kemijske kinetike zgorevanja sinteznega plina z upoštevanjem vpliva klorovih in žveplovih spojin Development of a chemical kinetic mechanism for syngas combustion incorporating the effects of chlorine and sulphur compounds Obstoječi reakcijski mehanizmi zgorevanja sinteznega plina obravnavajo le klorove ali le žveplove spojine, kar omejuje njihovo napovedljivost. V nalogi smo definirali enoten reakcijski mehanizem, ki obravnava zgorevanje sinteznega plina ob hkratni prisotnosti klorovih in žveplovih spojin, ter ustrezno napove vplive teh spojin. Združen mehanizem smo nato reducirali in pridobili mehanizem, primeren za uporabo v 3D CFD simulacijah. Oba mehanizma sta bila validirana glede na podatke iz literature. Mehanizma omogočata izboljšano napoved zgorevanja sinteznega plina ob prisotnosti klorovih in žveplovih spojin. Existing reaction mechanisms for the combustion of syngas consider only chlorine or only sulphur compounds, which limits their predictive ability. In this study, we defined a unified reaction mechanism that considers the syngas combustion in the simultaneous presence of chlorine and sulphur compounds and accurately predicts the effects of these compounds. We reduced the combined mechanism to obtain a mechanism suitable for use in 3D CFD simulation. Both mechanisms were validated based on data from literature. The mechanisms enable improved predictions of syngas combustion in the presence of chlorine and sulphur compounds. sintezni plin modeliranje zgorevanja mehanizmi kemijske kinetike redukcija mehanizmov kemijske kinetike tvorba polutantov uplinjanje odpadkov syngas combustion modelling mechanism of chemical kinetics reduction of chemical kinetics mechanisms formation of pollutants gasification waste true false false [L. Ratajc] Slovenski jezik Angleški jezik Magistrsko delo/naloga 2026-09-12 08:30:45 2026-09-12 08:30:47 2026-09-17 11:38:00 0000-00-00 00:00:00 2026 0 Ljubljana 0 XX, 84 str. 0000-00-00 NiDoloceno NiDoloceno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 662.76:544.43(043.2) 290299 291426819 49366.pdf 49366.pdf 1 597FF5E68C85273277C1F603F8BB0144 b6d0e09b67cb9e2876d5d9bc0e4c544236d954611c8ef9dbf2125df0a1c2791e 768efe58-ae73-11f1-8bc5-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=247337 Fakulteta za strojništvo 0 0 0