20.500.12556/RUL-186753 Sinteza piritionov z dušik vsebujočimi funkcionalnimi skupinami in priprava njihovih kompleksov z izbranimi prehodnimi kovinami Synthesis of pyrithiones with nitrogen containing functional groups and preparation of their selected transition metal complexes V magistrskem delu je predstavljena sinteza novih analogov piritiona z aminsko skupino na mestih 3, 4 ali 5, ali z nitro skupino na mestih 3 ali 5. Izhajala sem iz 2-kloropiridinov z nitro skupino na različnih mestih. Amino analoge sem pridobila z Zininovo redukcijo. S sintetiziranimi piritioni sem pripravila komplekse, ki vsebujejo bakrove, cinkove, zlatove, rutenijeve ali renijeve ione. Vsi ligandi in kompleksi, opisani v tem delu, so nove spojine. Te sem karakterizirala s pomočjo NMR spektroskopije, masne spektrometrije (HRMS), CHN elementne analize, IR in UV-Vis spektroskopije. V primeru nekaterih spojin sem pridobila kristale, ki so bili analizirani s pomočjo rentgenske strukturne analize (XRD). The aim of my work was to synthesize new pyrithione analogues with an amino group at positions 3, 4, or 5, or a nitro group at positions 3 or 5. In the pyrithione synthesis, the products were obtained from 2-chloropyridines with nitro group at the corresponding positions. The amino analogues were prepared by Zinin reduction. The resulting pyrithiones were coordinated in complexes with copper, zinc, gold, ruthenium, or rhenium ions. All ligands and complexes described in this work are novel compounds. They were characterised by NMR spectroscopy, mass spectrometry (HRMS), CHN elemental analysis, IR, and UV-Vis spectroscopy. In some cases, I was able to obtain single crystals, which were analysed using X-ray diffraction (XRD). aminopiritioni nitropiritioni Zininova redukcija kompleksi kovin d-bloka aminopyrithione nitropyrithione Zinin reduction d-block metal complexes true false false Slovenski jezik Angleški jezik Magistrsko delo/naloga 2026-09-04 13:45:11 2026-09-04 13:45:18 2026-09-05 04:34:27 0000-00-00 00:00:00 2026 0 0 0000-00-00 NiDoloceno NiDoloceno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 1970-01-01 26103 Lakota_Katarina_lucija_-_Sinteza_piritionov_z_dusik_vsebujocimi_funkcionalnimi_skupinami_in_prip.pdf Lakota_Katarina_lucija_-_Sinteza_piritionov_z_dusik_vsebujocimi_funkcionalnimi_skupinami_in_prip.pdf 1 04CEA0D78824320400F344E5B025C3CF f5f56c920bdd16b8a19bb9b336b6e5497effe853a0bb095a5ee9a3bbad59f54e 198ef891-a856-11f1-8bc5-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=246118 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0