20.500.12556/RUL-181557 Polymethylenetetrazole synthesis, characterization, and energetic properties The tetrazole moiety remains one of the most interesting scaffolds in the development of new high-energy density materials (HEDMs) because of its desired characteristics, such as high nitrogen content and heat of formation (HOF). The combination of several heterocycles with high HOF seems to be a promising strategy for obtaining energetic materials with superior properties. Herein, we report the synthesis and characterization of a tetrazole polymer, polymethylenetetrazole (PMT), as a potential HEDM. The compound was characterized using NMR, IR, and Raman spectroscopy. Its weight average molecular mass was obtained by static light scattering (SLS), and its physical properties by powder XRD analysis. The density, sensitivity to friction (FS), and impact (IS) of the compound were determined as well. The results of the thermal and energetic properties of PMT suggest that this polymer could be an insensitive explosive. tetrazoles polymers high-energy density materials tetrazoli polimeri materiali z visoko energijsko gostoto true false true Angleški jezik Slovenski jezik Članek v reviji 2026-04-10 11:09:40 2026-04-10 11:09:40 2026-04-13 04:41:49 0000-00-00 00:00:00 2024 0 0 13 str. iss. 14, art. 3389 Vol. 29 Jul. 2024 0000-00-00 Zaloznikova Objavljeno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 547.79:678 1420-3049 10.3390/molecules29143389 270394371 RAZ_Brenjo_Ljubica_2024.pdf RAZ_Brenjo_Ljubica_2024.pdf 1 DE7EBA6524CF451D74AFF81C0DA46EAE 9e1a26dbed487850ab3097992c3aab441e6c427a4093974fb7af032420a153e8 7f6c10bd-34bd-11f1-b0ab-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=232196 https://www.mdpi.com/1420-3049/29/14/3389 1 cd35b70d-34bc-11f1-b0ab-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=232195 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0