20.500.12556/RUL-181382 Investigating plastic-metal interactions in aquatic environments using laser ablation ICP-MS and chemical markers Plastics in aquatic environments interact with metals, influencing their fate and transport. Biotic aging of plastics plays a pivotal role in this process, but the mechanisms are still unclear. Here, we employed laser ablation–inductively coupled plasma mass spectrometry (LA–ICP–MS) to track elemental cross-sectional distribution in biotically aged plastics and assess metal enrichment within the biofilm. Copper, sorbed from the water environment, was used as a marker of biofilm presence, while antimony and tin marked the plastic phase for polyethylene terephthalate (PET) and polylactic acid (PLA), respectively. Aged samples revealed distinct metal distribution patterns tracking copper enrichment on the surface, whereas physicochemical changes happened on the plastic surface after aging, highlighting the biofilm presence. Copper depletion in water during the aging experiment confirmed that aged plastics accumulate this metal, showing the key role of biofilms in governing this process. Conventional analysis based on acid digestion of plastic fragments only partially captured this enrichment, underscoring the added value of LA–ICP–MS to specifically track metals accumulated from the water in comparison to those present in the polymer matrix. These results highlight the need to account for biofilm-mediated processes in risk assessments and establish LA–ICP–MS as a powerful tool for investigating metal–plastic interactions. pollution aging biofouling sorption additives environmental risk plastisphere onesnaževanje staranje biološko obraščanje sorpcija aditivi okoljsko tveganje plastisfera true false true Angleški jezik Slovenski jezik Članek v reviji 2026-04-03 11:48:23 2026-04-03 11:48:25 2026-04-07 12:07:31 0000-00-00 00:00:00 2026 0 0 Str. 1925-1935 iss. 3 Vol. 6 13 Mar. 2026 0000-00-00 Zaloznikova Objavljeno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 502.51:504.5 2690-0637 10.1021/acsestwater.5c01387 273097987 RAZ_Spanu_Davide_2026.pdf RAZ_Spanu_Davide_2026.pdf 1 4E0DB3490D8EE5F5FA2E97E45796DC02 9c239bdf7d812ec2ea059c1f1e5c436778ac4576808de758e152853fd3c2975a 6733e929-2f43-11f1-b0ab-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=231796 https://pubs.acs.org/doi/10.1021/acsestwater.5c01387 1 18479b36-2f42-11f1-b0ab-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=231795 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0