20.500.12556/RUL-175827 One-step copper-assisted synthesis of $\alpha$-(styrylsulfonyl)amides via ▫$SO_2$▫ incorporation under visible light α-(Styrylsulfonyl)amides and their related ester analogs are an important class of substances that have been widely used as precursors toward bioactive compounds. While most existing methods for the preparation of related compounds include either multiple steps or the use of precious metals, the method presented in this paper utilizes copper and visible light to produce α-(styrylsulfonyl)amides and α-(styrylsulfonyl)esters from α-bromoamides or esters, SO$_2$ and styrenes in moderate to high yield in a single step. The mechanism of the newly developed method is investigated and likely differs from related methods for the photocatalyzed fixation of SO$_2$ into organic scaffolds. photoredox catalysis sulfur dioxide sulfones copper catalysis copper complexes fotoredoks kataliza žveplov dioksid sulfoni bakrova kataliza bakrovi kompleksi true false true Angleški jezik Slovenski jezik Članek v reviji 2025-11-10 12:45:13 2025-11-10 12:45:17 2026-04-01 04:30:00 0000-00-00 00:00:00 2025 0 0 7 str. iss. 24, art. e70196 Vol. 367 22 Dec. 2025 0000-00-00 Zaloznikova Objavljeno apc 0000-00-00 0000-00-00 0000-00-00 547.551.52:544.526.5 1615-4150 10.1002/adsc.70196 255761411 RAZ_Petek_Nejc_2025.pdf RAZ_Petek_Nejc_2025.pdf 1 BFAF9EB14CFD4A708EDC6351E8B92707 a7aed2b48d8afc8e4256faabcf3f7781029de04c6a8d943d4cf062e7f3267347 a63a2a99-2cd8-11f1-b0ab-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=231611 https://advanced.onlinelibrary.wiley.com/doi/10.1002/adsc.70196 1 669b1366-be2a-11f0-9328-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=221714 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0