20.500.12556/RUL-171941 Sinteza z adamantanom substituirane triazolijeve soli Synthesis of an adamantane-substituted triazolium salt Cilj diplomske naloge je bil sinteza 1,3,4,5-tetrasubstituirane-1H-1,2,3-triazolijeve soli, ki vsebuje adamantan kot vsaj enega izmed substituentov. Za seznanitev s koraki sinteze smo najprej sintetizirali 1-(4-metilfenil)-3,4-difenil-5-metil-1H-1,2,3-triazol-3-ijev triflat. Po optimizaciji klik reakcije med 1-azidoadamantanom in fenilacetilenom smo na majhni skali smo uspešno sintetizirali 1-(adamantan-1-il)-3,4-difenil-1H-1,2,3-triazol-3-ijev triflat in 1-(adamantan-1-il)-3,4-difenil-5-metil-1H-1,2,3-triazol-3-ijev triflat. Te tri nove spojine smo okarakterizirali z jedrsko magnetno resonanco, infrardečo spektroskopijo in masno spektrometrijo ter jim določili tališča. The aim of this Bachelor's thesis was synthesis of 1,3,4,5-tetrasubstituted-1H-1,2,3-triazolium salt containing adamantane moiety as at least one of the substituents. To familiarize with the synthesis process, we first synthesized 1-(4-methylphenyl)-3,4-diphenyl-5-methyl-1H-1,2,3-triazol-3-ium triflate. After optimizing the click reaction between 1-azidoadamantane and phenylacetylene, we successfully synthesized 1-(adamantan-1-yl)-3,4-diphenyl-1H-1,2,3-triazol-3-ium triflate and 1-(adamantan-1-yl)-3,4-diphenyl-5-methyl-1H-1,2,3-triazol-3-ium triflate on a small scale. We characterized these three novel compounds with nuclear magnetic resonance, infrared spectroscopy, and mass spectrometry; their melting points were also determined. triazolijeva sol adamantan klik reakcija triazolium salt adamantane click reaction true false false Slovenski jezik Angleški jezik Diplomsko delo/naloga 2025-09-04 10:20:00 2025-09-04 10:20:04 2025-10-16 09:53:52 0000-00-00 00:00:00 2025 0 0 0000-00-00 NiDoloceno NiDoloceno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 22853 253415427 Rener_Ambroz_-_Sinteza_z_adamantanom_substituirane_triazolijeve_soli.pdf Rener_Ambroz_-_Sinteza_z_adamantanom_substituirane_triazolijeve_soli.pdf 1 E9D29C5769AD56F343C05F5463DCEE64 cb9c257adf3961d7bdf9c2980bdba2a4df2a10897bf6a8a67830f5458a7ff808 d0ca55e3-8967-11f0-9328-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=215525 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0