20.500.12556/RUL-168897 Assessing silicate catchment dynamics of the Oplotnica River (Slovenia) through stable carbon and nitrogen isotopes This study investigated the sources of carbon and nitrogen in a small, silicate-dominated catchment (Oplotnica River, Pohorje, Slovenia) with two creeks, Lukanjski and Javorski, from 2012 to 2014. Additionally, carbon and nitrogen cycling in soil profiles was studied at Javorski Creek. Isotopic analyses of river water, particulates, and sediments provided a more holistic view of the sources of carbon and nitrogen, weathering contributions, and the evasion or sequestration of CO$_2$ in the atmosphere within the catchments. The weathering of rocks, such as granodiorite and quartz diorite, influences water geochemistry. The Oplotnica River and its tributaries were characterized by the ion composition: Na$^+$ > Ca$^{2+}$ > Mg$^{2+}$ > K$^+$ and HCO$_3$$^−$ > SO$_4$$^{2−}$ > Cl$^−$ > NO$_3$$^−$. Partial pressure of CO$_2$ concentrations in river and creeks ranged from 1.1 to 13.4 times that of atmospheric pressure, representing a source of CO$_2$ to the atmosphere. The carbon isotope value of dissolved inorganic carbon (δ$^{13}$C$_{DIC}$) ranged from −9.8 to −1.4‰ in river, while in the creeks, it ranged from −26.1 to −4.7‰, reflecting the degradation of organic matter and exchange with the atmosphere. The intensity of bicarbonate weathering for the Oplotnica River at its gauging station was 10.4 mmol/(l⋅km$^2$⋅s), characteristic of silicate watersheds. The isotopic composition of carbon (δ$^{13}$C) and nitrogen (δ$^{15}$N) in river sediments reflects values typical of soil and temperate (C3) plants. This study is significant on both local and global levels, as it addresses the contribution of weathering rates and the release of CO$_2$ to the atmosphere from small silicate watersheds. river systems silicate catchment water–soil interactions stable isotopes weathering intensity Oplotnica River reke sistemi izotopi true false true Angleški jezik Slovenski jezik Članek v reviji 2025-05-06 11:12:41 2025-05-06 11:12:45 2025-05-07 04:05:41 0000-00-00 00:00:00 2025 0 0 33 str. iss. 1, art. 5 Vol. 31 2025 0000-00-00 Zaloznikova Objavljeno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 502/504 1573-1421 10.1007/s10498-025-09439-w 234492675 s10498-025-09439-w_(1).pdf s10498-025-09439-w_(1).pdf 1 34FE07EDF01D2FF288B7895705D5B89C afa5e7eaf97dac34ca82ffaf91698c72d414c953cfc7632a40b494b6e23f74f3 59c5bb9c-2a59-11f0-b232-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=209980 https://link.springer.com/article/10.1007/s10498-025-09439-w 1 172efbd6-2a59-11f0-b232-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=209979 Naravoslovnotehniška fakulteta 0 0 0