20.500.12556/RUL-167546 Melting temperature hidden behind liquid−liquid phasetransition in glycerol Liquid−liquid phase transitions play a pivotal role in various scientific disciplines andtechnological applications, ranging from biology to materials science and geophysics. Understanding thebehavior of materials undergoing these transitions provides valuable insights into complex systems and theirdynamic properties. This review explores the implications of liquid−liquid phase transitions, particularlyfocusing on the transition between low-density liquid (LDL) and high-density liquid (HDL) phases. Weinvestigate the thermodynamic, structural, and mechanistic aspects of these transitions, emphasizing theirrelevance in diverse fields. The creation of dynamic heterogeneities and critical fluctuations during liquid−liquid phase transitions is discussed, highlighting their role in shaping the phase behavior and dynamics ofcomplex fluids. Experimental observations, including the use of dielectric spectroscopy and nonlinearmethods, shed light on the intricate nature of these transitions. Our findings suggest a connection between liquid−liquid phasetransitions and critical phenomena, with implications for understanding the supercooled state and phase behavior of hydrogen-bonded liquids such as glycerol. Overall, this review underscores the importance of interdisciplinary approaches in unraveling thecomplexities of liquid−liquid phase behavior and addressing fundamental questions. glycerol phase transition melting critical fluctuations glicerol fazni prehod taljenje kritične fluktuacije true false true Angleški jezik Slovenski jezik Članek v reviji 2025-02-27 10:49:10 2025-02-27 10:49:16 2025-02-28 04:00:11 0000-00-00 00:00:00 2025 0 0 Str. 1670-1674 iss. 5 Vol. 129 2025 0000-00-00 Zaloznikova Objavljeno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 577 1520-5207 10.1021/acs.jpcb.4c04552 224468227 starzonek-et-al-2025-melting-temperature-hidden-behind-liquid-liquid-phase-transition-in-glycerol.pdf starzonek-et-al-2025-melting-temperature-hidden-behind-liquid-liquid-phase-transition-in-glycerol.pdf 1 9A8EDA4942C7C9922A71B2582CEC5826 03d2de3e343fb4450570f7c33079d01a5fb4007d60d6bb3a908a4d5abba979d9 5adc06d7-f4ef-11ef-b232-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=200175 https://pubs.acs.org/doi/10.1021/acs.jpcb.4c04552 1 30aeabf8-f4ef-11ef-b232-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=200174 Fakulteta za elektrotehniko 0 0 0