20.500.12556/RUL-156103 Sinteza izbranih enaminoketonov in njihova uporaba v določenih fotokemijskih pretvorbah Synthesis of selected enaminoketones and their use in different photochemical transformations Enaminoketoni so pomembna skupina organskih spojin, ki nastopajo v mnogih reakcijah organske sinteze, kot je na primer sinteza heterocikličnih spojin. Iz enaminoketonov lahko pripravimo β-ketoiminatne komplekse. Ti kompleksi imajo zanimive optične lastnosti, kar nakazuje tudi na njihovo možno uporabnost v fotokemijskih transformacijah, ki so zaenkrat slabo raziskane. Zato sem poskusil razviti nove fotokemijske pretvorbe teh spojin. Ker so bile te reakcije le delno uspešne, sem se osredotočil na izhodne enaminoketone kot substrate za fotokemijske pretvorbe. Na tem področju sem bil bolj uspešen in sem naredil začetne poskuse za razvoj novih fotokemijskih transformacij na teh spojinah. Hkrati sem enaminoketone reagiral s klorosulfonil izocianatom, da sem pridobil substrate za fotoredoks reakcije. Enaminoketones are an important class of organic compounds with versatile applicability in organic synthesis, in particular in the synthesis of heterocyclic compounds. β-Ketoiminate complexes can be derived from the aforementioned compounds. These complexes have interesting optical properties, which suggest their possible use as substrates in photochemical transformations, which remain under-examined. This led to the attempt to develop new photochemical transformations of these compounds. Unfortunately, despite efforts, this achievement was elusive, thus I decided to focus on the starting enaminoketones as potential substrates for photochemical transformations. The efforts were successful, and the groundwork was laid for the development of novel photochemical reactions of these compounds. In parallel with the main topic, the aforementioned compound was reacted with chlorosulfonyl isocyanate, thus producing potential substrates for photoredox reactions. enaminoketoni β-ketoiminatni kompleksi fotokemija fotoredoks pretvorbe enaminoketones β-ketoiminate complexes photochemistry photoredox conversions true false false Slovenski jezik Angleški jezik Magistrsko delo/naloga 2024-05-08 11:40:02 2024-05-08 11:40:07 2024-05-17 12:46:29 0000-00-00 00:00:00 2024 0 0 0000-00-00 NiDoloceno NiDoloceno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 22766 195796483 Jarc_rydzi_Matej_-_Sinteza_izbranih_enaminoketonov_in_njihova_uporaba_v_dolocenih_fotokemijskih_.pdf Jarc_rydzi_Matej_-_Sinteza_izbranih_enaminoketonov_in_njihova_uporaba_v_dolocenih_fotokemijskih_.pdf 1 69ECBE3536954663C37DD577F75CB062 e2a139875cfc58fd55fcc966f030e661e02d30c51725f48cd5a96299f1580e3d f5a2fa3f-0d1e-11ef-a389-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=183343 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0