20.500.12556/RUL-149546 KINALDINSKA KISLINA KOT KATION V NEKATERIH FLUORIDOMETALATNIH SOLEH QUINALDIC ACID AS CATION IN SOME FLUORIDOMETALATE SALTS Delo temelji na sintezi in karakterizaciji spojin kinaldinske kisline in nekaterih fluoridometalatov: heksafluoridosilikatov(IV), heksafluoridotitanatov(IV) in pentafluoridooksidovanadatov(V). Za vsak fluoridometalat so bile opravljene tri sintezne reakcije med kinaldinsko kislino in ustreznim oksidom v razmerju 1:2, 1:1 in 1:0,5. Vse reakcije so potekale v vodni raztopini fluorovodikove kisline. Produkti reakcij so bili analizirani z infrardečo spektroskopijo, nuklearno magnetno resonančno spektroskopijo, elementno analizo in rentgensko strukturno analizo. S pomočjo rentgenske strukturne analize sta opisani kristalni strukturi dveh spojih, ki doslej še nista bili objavljeni: 2-karboksikinolinijev fluorid in 2-karboksikinolinijev heksafluoridotitanat. A research is based on a synthesis and characterization of quinaldic acid and some fluoridometalate compounds [hexafluoridosilicate(IV), hexafluoridotitanate(IV) and pentafluoridooxidovanadate(V)]. Three synthesis reactions between quinaldic acid and the corresponding oxide were carried out for each fluoridometalate in a stoichiometric ratio of 2:1, 1:1 and 0.5:1. All reactions were carried out in aqueous hydrofluoric acid solution. Reaction products were analysed by infrared spectroscopy, nuclear magnetic resonance spectroscopy, elemental analysis and X-ray structural analysis. Two unpublished novel compounds, namely 2-carboxyquinolinium fluoride and 2-carboxyquinolinium hexafluorotitanate, were described by the X-ray structural analysis. kinaldinska kislina fluoridometalati indrardeča spektroskopija rentgenska strukturna analiza quinaldic acid fluoridometalates infrared spectroscopy X-ray structural analysis true false false Slovenski jezik Angleški jezik Diplomsko delo/naloga 2023-09-07 11:26:50 2023-09-07 11:26:51 2023-09-14 14:08:12 0000-00-00 00:00:00 2023 0 0 0000-00-00 NiDoloceno NiDoloceno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 22686 164466691 Luksic_Andraz_-_KINALDINSKA_KISLINA_KOT_KATION_V_NEKATERIH_FLUORIDOMETALATNIH_SOLEH.pdf Luksic_Andraz_-_KINALDINSKA_KISLINA_KOT_KATION_V_NEKATERIH_FLUORIDOMETALATNIH_SOLEH.pdf 1 EEBF4E0D51E7325AB758A69D954406FC 818569b059de0f3417761880122ddfc36494fefaab9939388d317a7bef94f5d0 ab93a990-4d60-11ee-9934-0050569b8976 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=174030 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0