20.500.12556/RUL-145622 Dvojedrne koordinacijske spojine bakra(II) z alkoholamini Dinuclear copper(II) complexes with alcoholamines Enojedrno koordinacijsko spojino bakra(II) s kinaldinatom, [Cu(quin)2(H2O)], smo pri različnih pogojih reagirali z dvema alkoholaminoma, dietanolaminom (deaH2) in N-metildietanolaminom (Me-deaH2). V obeh primerih sta nastali dvojedrni spojini, v primeru dietanolamina [Cu2(quin)2(deaH)2)], v primeru N-metildietanolamina pa [Cu2(quin)3(Me-deaH)]·2MeOH. Na bakrove(II) ione je koordinirana anionska oblika alkoholamina, ki nastane z deprotonacijo hidroksilne skupine. Preučevali smo vpliv reakcijskih pogojev in topilnega sistema na naravo produktov. Mononuclear copper(II) complex with quinaldinate, [Cu(quin)2(H2O)], was reacted with two alcoholamines, diethanolamine (deaH2) and N-methyldiethanolamine (Me-deaH2). Reaction conditions were also varied. Dinuclear copper(II) complexes were obtained for both ligand systems, [Cu2(quin)2(deaH)2)] for diethanolamine and [Cu2(quin)3(Me-deaH)]·2MeOH for N-methyldiethanolamine. Anionic forms of alcoholamines were found coordinated to copper(II) ions. The anions form on the deprotonation of hydroxyl moiety. Influence of the reaction conditions over the nature of the product was also studied. baker(II) koordinacijska kemija alkoholamini copper(II) coordination chemistry alcoholamines true false false Slovenski jezik Angleški jezik Diplomsko delo/naloga 2023-04-26 14:55:00 2023-04-26 14:55:05 2023-05-24 12:52:29 0000-00-00 00:00:00 2023 0 0 0000-00-00 NiDoloceno NiDoloceno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 22623 153290499 Cresnovar_Erik_-_Dvojedrne_koordinacijske_spojine_bakra(II)_z_alkoholamini.pdf Cresnovar_Erik_-_Dvojedrne_koordinacijske_spojine_bakra(II)_z_alkoholamini.pdf 1 73952E6AE37D297C6F23682E2BE9FF8F c270621134360cb89866e291c1e85c405ef7ede3570554ce7abd748e5a97c43b 6057644a-e431-11ed-a314-00155dcfd717 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=168567 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0