20.500.12556/RUL-141158 Improvement of biotreatability of environmentally persistent antibiotic Tiamulin by O$_3$ and O$_3$/H$_2$O$_2$ oxidation processes The aim of the work was to assess the efficiency of ozonation and ozonation in combination with H$_2$O$_2$ in jet loop reactor to increase biotreatability of persistent veterinary antibiotic Tiamulin. The efficiency of oxidative processes was monitored by combined approach based on determination of efficiency of wastewater treatment and impact to waste sludge stabilization. Degradation of Tiamulin in model wastewater (100 mg L$^{−1}$) during oxidation was followed by COD and DOC measurements while changes in biodegradability were determined by respirometric measurements. Biogas production potential was also determined to identify problems related to anaerobic digestion of waste sludge resulted in treatment of Tiamulin-contaminated wastewater. At ozone dose of 69 g$_{ozone}$ g$_{COD}^{−1}$ and 220 g$_{ozone}$ g$_{DOC}^{−1}$removal for COD and DOC was 26% and 17%, respectively. Better biotreatability was confirmed by respirometric testing. H$_2$O$_2$ addition did not improve removal efficiency (11–13%). The second stage of nitrification was suppressed by the addition of Tiamulin and ozonation again recovered N-NO$^−_3$ formation. O$_3$/H$_2$O$_2$ treated sample reduced the nitrification, especially formation of N-NO$^−_2$ in the first phase of the process. Simultaneously, quadratic model was developed to describe the relationship between oxygen uptake rate and changes in ammonium nitrogen concentration due to the oxidative treatment. The positive impact of ozone was also confirmed by ozonation of Tiamulin-contaminated (400 mg L$^{−1}$) waste sludge where biogas production potential was increased for 6-times. Combination of approaches confirmed, that O$_3$ effectively increase the treatability of Tiamulin in wastewater and sludge while addition of the hydrogen peroxide generally did not improve the performance of the processes. biotreatability nitrification respirometry ozonation Tiamulin sposobnost biološkega čiščenja nitrifikacija respirometrija ozonacija Tiamulin true false true Angleški jezik Slovenski jezik Članek v reviji 2022-09-23 15:36:29 2022-09-23 15:36:30 2022-09-27 03:10:34 0000-00-00 00:00:00 2022 0 0 Str. 2319-2328 no. 15 Vol. 43 2022 0000-00-00 Zaloznikova Objavljeno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 628.349:66.094.3-926.214 0959-3330 10.1080/09593330.2021.1876776 50140931 Improvement_of_biotreatability_of_environmentally_persistent_antibiotic_Tiamulin_by_O3_and_O3_H2O2_oxidation_processes.pdf Improvement_of_biotreatability_of_environmentally_persistent_antibiotic_Tiamulin_by_O3_and_O3_H2O2_oxidation_processes.pdf 1 1BF25FF032F5E82788FF5C4B36D0A4ED 6d14adf2c9699c6d12bb55195848339f2a9a977625013dc3cb4a3f8e88f68f27 f181e2fc-3b44-11ed-9c94-00155dcfd717 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=162088 https://www.tandfonline.com/doi/full/10.1080/09593330.2021.1876776 1 bd4cfaa6-3b44-11ed-9c94-00155dcfd717 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=162087 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0