20.500.12556/RUL-139702 Optimizacija sinteze izbranih derivatov piritiona in priprava njihovih cinkovih koordinacijskih spojin Optimisation of synthesis of selected pyrithione derivatives and preparation of their coordination compounds with zinc Cilj diplomske naloge je bila optimizacija že znane sintezne poti za pripravo piritionov s trifluorometilno skupino in uporaba le-teh za sintezo cinkovih koordinacijskih spojin. Pri eksperimentalnem delu so bili sintetizirani štirje analogi piritiona s trifluorometilno skupin na različnih položajih aromatskega obroča, ki so bili nato uporabljeni kot ligandi za sintezo cinkovih koordinacijskih spojin. Sintetizirani piritioni in njihovi cinkovi kompleksi so bili karakterizirani z jedrsko magnetno resonanco (NMR) ter z UV-Vis in IR spektroskopijo. Pripravljeni piritioni so bili dodatno karakterizirani tudi z masno spektrometrijo. The aim of my work was to optimize an already known synthetic route of pyrithiones with trifluoromethyl group and to prepare their coordination compounds with zinc. Four different pyrithione analogues with different positions of the trifluoromethyl group on the aromatic ring were synthesized and later used as ligands for the preparation of zinc complexes. The synthesized pyrithiones and their zinc complexes were characterized by nuclear magnetic resonance (NMR), UV-Vis and IR spectroscopy. The pyrithiones were also characterized by mass spectrometry. optimizacija substituirani piritioni fluor cink optimisation substituted pyrithiones fluorine zinc true false false Slovenski jezik Angleški jezik Diplomsko delo/naloga 2022-09-06 13:05:17 2022-09-06 13:05:19 2022-10-19 10:46:59 0000-00-00 00:00:00 2022 0 0 0000-00-00 NiDoloceno NiDoloceno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 22127 126254595 Poljanc_Benjamin_-_Optimizacija_sinteze_izbranih_derivatov_piritiona_in_priprava_njihovih_cinkov.pdf Poljanc_Benjamin_-_Optimizacija_sinteze_izbranih_derivatov_piritiona_in_priprava_njihovih_cinkov.pdf 1 3659421A3A647170B9A34A401A6C6640 9edb3b8c83ddba51a0475870bf078489da62daa91fe2d9f3d30f5eec8cd70c25 bec3edd5-2dd3-11ed-92af-00155dcfd717 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=160306 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0