20.500.12556/RUL-137419 Sinteza kelatnih S-metiliranih tiopirimidinov Synthesis of chelated S-methylated thiopyrimidines Namen diplomske naloge je bil izvesti reakcije med enaminoni in S-metil tiosečnino za pripravo S- metiliranih pirimidin-2-tionov oz. pripraviti metilirane pirimidin-2-tionske substrate z S-metilacijo z ustreznimi metilirajočimi reagenti, ter izvesti poskusne reakcije sintetiziranega metiliranega pirimidin-2-tionskega substrata za sintezo kovinskih kompleksov. V okviru diplomske naloge sem sintetizirala S-metiliran pirimidin-2-tionski substrat in pripravila dva kompleksa. Sintetiziran S-metiliran pirimidin-2-tionski substrat je bil karakteriziran z jedrsko magnetno resonanco (NMR), masno spektrometrijo (HRMS) in rentgensko difrakcijo, kompleksi pa z jedrsko magnetno resonanco (NMR) in masno spektrometrijo (HRMS). The purpose of my thesis was to prepare methylated pyrimidine-2-thiones using methylating agents or by reacting enaminones with S-methyl thiourea, and to perform test reactions with methylated pyrimidine-2-thione substrates to synthesize metal complexes. A S-methylated pyrimidine-2-thione substrate and two complexes were prepared. S-methylated substrate was characterized with nuclear magnetic resonance (NMR), mass spectrometry (HRMS) and X-ray diffraction. Complexes were characterized with nuclear magnetic resonance (NMR) and mass spectrometry (HRMS). metiliranje pirimidin-2-tion S-metil tiosečnina kovinski kompleksi methylation pyrimidine-2-thione S-methyl thiourea metal complexes true false false Slovenski jezik Angleški jezik Diplomsko delo/naloga 2022-06-16 10:35:00 2022-06-16 10:35:02 2022-09-15 04:15:05 0000-00-00 00:00:00 2022 0 0 0000-00-00 NiDoloceno NiDoloceno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 20521 112006915 Stopar_Zala_-_Sinteza_kelatnih_S-metiliranih_tiopirimidinov.pdf Stopar_Zala_-_Sinteza_kelatnih_S-metiliranih_tiopirimidinov.pdf 1 0F86B3CDBBBDB5E211ACD09F895C551B 1b658f84f7d9857187d12b3cb1edca26248786d91c7b94fd5ba107fa9849e252 0960f973-ed4f-11ec-8aca-00155dcfd717 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=157351 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0