20.500.12556/RUL-137272 Detection and characterization of TiO$_2$ nanomaterials in sludge from wastewater treatment plants of Chihuahua State, Mexico TiO$_2$ nanoparticles (TiO$_2$-NPs) have a wide range of industrial applications (paintings, sunscreens, food and cosmetics) and is one of the most intensively used nanomaterials worldwide. Leaching from commercial products TiO$_2$-NPs are predicted to significantly accumulate in wastewater sludges, which are then often used as soil amendment. In this work, sludge samples from four wastewater treatment plants of the Chihuahua State in Mexico were obtained during spring and summer (2017). A comprehensive characterization study was performed by X-ray based (laboratory and synchrotron) techniques and electron microscopy. Ti was detected in all sludge samples (1810–2760 mg/kg) mainly as TiO$_2$ particles ranging from 40 nm up to hundreds of nm. MicroXANES data was analyzed by principal component analysis and linear combination fitting enabling the identification of three predominant Ti species: anatase, rutile and ilmenite. Micro-XANES from the smaller Ti particles was predominantly anatase (68% + 32% rutile), suggesting these TiO$_2$-NPs originate from paintings and cosmetics. TEM imaging confirmed the presence of nanoscale Ti with smooth surface morphologies resembling engineered TiO$_2$-NPs. The size and crystalline phase of TiO$_2$-NPs in the sludge from this region suggest increased reactivity and potential toxicity to agro-systems. Further studies should be dedicated to evaluating this. nanoparticles sewage sludge X-ray microspectroscopy synchrotron true false true Angleški jezik Ni določen Članek v reviji 2022-06-09 10:19:02 2022-06-09 10:19:04 2022-09-15 04:14:53 0000-00-00 00:00:00 2022 0 0 21 str. iss. 5, art. 744 Vol. 12 2022 0000-00-00 Zaloznikova Objavljeno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 549.514.6 2079-4991 10.3390/nano12050744 98738179 nanomaterials-12-00744.pdf nanomaterials-12-00744.pdf 1 2DF3C6BC877775111E752BCCD66E1DE6 dcc7bfa8fa9ab318185aaf6af36b97d1194d6c310ba70d9387a7517189307c04 ad429106-e7cf-11ec-8aca-00155dcfd717 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=157178 https://www.mdpi.com/2079-4991/12/5/744 1 a9c918f9-e7cc-11ec-8aca-00155dcfd717 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=157173 Biotehniška fakulteta 0 0 0