20.500.12556/RUL-135669 Manganove in nikljeve spojine z vinsko kislino Manganese and nickel compounds with tartaric acid Poiskal sem članke z opisi nekaterih manganovih in nikljevih spojin z anionom vinske (tartarne) kisline (C4H6O6 = H4L). V njih sem našel tri manganove in dve nikljevi spojini. To so: Na5[Mn(L)2](H2O)12 (1), {[Ni2(H2L)2(H2O)2](H2O)3}n (2), {[Mn2(H2L)2(H2O)](H2O)3}n (3), {[Mn(H2L)(H2O)](H2O)}n (4) in [Ni4(H2L)4(H2O)8](EtOH)0,5(H2O)10,25 (5). Te spojine so avtorji sintetizirali in jih analizirali. Njihovo strukturo in sestavo so okarakterizirali s elementno analizo, rentgensko strukturno analizo, IR spektroskopijo in termično analizo. Spojine so z M2+ in H2L2- in molekulske (koordinacijske enote so nevtralne) razen spojina 1, ki je ionska, z Mn3+ in z L4-. Strukture vseh spojin so stabilizirane z vodikovimi vezmi prek tartarnega liganda in molekul vode. A search trough articles with descriptions of selected manganese and nickel compounds with the anion of the tartaric acid (C4H6O6 = H4L) was performed. Three manganese along with two nickel compounds were found. These are: Na5[Mn(L)2](H2O)12 (1), {[Ni2(H2L)2(H2O)2](H2O)3}n (2), {[Mn2(H2L)2(H2O)](H2O)3}n (3), {[Mn(H2L)(H2O)](H2O)}n (4) and [Ni4(H2L)4(H2O)8](EtOH)0.5(H2O)10.25 (5). The authors described their syntheses and characterisation. Their structures and composition were idenified with elemental analysis, X-ray structural analysis, IR spectroscopy and thermal analysis. Compounds are with M2+ and coordination moieties are molecular. An xception is ionic compound 1 H2L2- with Mn3+ and L4-. Structures of all compounds are stabilized with hydrogen bonds via tartrate ligand and water molecules. mangan nikelj vinska kislina koordinacijske spojine manganese nickel tartaric acid coordination compounds true false false Slovenski jezik Angleški jezik Diplomsko delo/naloga 2022-03-24 10:35:00 2022-03-24 10:35:02 2022-09-14 04:14:33 0000-00-00 00:00:00 2022 0 0 0000-00-00 NiDoloceno NiDoloceno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 14561 102165763 Trampus_Luka_-_Manganove_in_nikljeve_spojine_z_vinsko_kislino.pdf Trampus_Luka_-_Manganove_in_nikljeve_spojine_z_vinsko_kislino.pdf 1 79C0526F50A21A5B86498AA98A1EBA00 308bc8edbfd2b9ee817dac3ade369f1f6737420af53a20229261fdba2dd3412b abba0fdf-ab55-11ec-8aca-00155dcfd717 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=154893 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0