20.500.12556/RUL-129652 Bakrove(II) spojine z adipinsko kislino in dušikovimi donorskimi ligandi Copper(II) compounds with adipic acid and nitrogen donor ligands Opisanih je pet spojin {[Cu(L)(nia)2]•H2O}n 1, {[Cu(L)(3-apy)2]•(H2L)}n 2, [(Cu(N3)(H2O))2(L)]n 3, [Cu(L)(H2O)2]n 4 in [Cu3(L)2(OH)2(H2O)4]n 5 v sistemu bakrovih(II) spojin s koordiniranim anionom adipinske kisline (C6H10O4 = H2L) in dodatnim dušikovim ligandom. Spojinam so določili kristalne strukture ter z elementno analizo določili ujemanje eksperimentalnih vrednosti z izračunanimi vrednostmi teoretične sestave za posamezno spojino. Vse spojine so polimerne. Povsod je mostovni ligand adipinat. Prisotnost ligandov se sklada z IR spektri, magnetne lastnosti z Cu(II) ter elektronski spektri z barvami spojin. Five compounds, namely {[Cu(L)(nia)2]•H2O}n 1, {[Cu(L)(3-apy)2]•(H2L)}n 2, [(Cu(N3)(H2O))2(L)]n 3, [Cu(L)(H2O)2]n 4 and [Cu3(L)2(OH)2(H2O)4]n 5 in a system of copper(II) compounds with a coordinated anion of adipic acid (C6H10O4 = H2L) along with additional nitrogen ligand are described. The crystal structures were determined for the compounds and the matching of the experimental values with the calculated ones of the theoretical composition for each compound was determined by elemental analysis. All compounds are polymeric. Adipinate ligand herein always serves as a bridging ligand. The ligand presence is in accordance with the IR spectra. Their magnetic properties agree with Cu(II) and the electronic spectra with the compounds' colours. baker(II) adipinska kislina struktura spojin IR copper(II) adipic acid structure of compounds IR true false false Slovenski jezik Angleški jezik Diplomsko delo/naloga 2021-09-06 12:41:42 2021-09-06 12:41:43 2022-09-08 04:09:52 0000-00-00 00:00:00 2021 0 0 0000-00-00 NiDoloceno NiDoloceno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 10981 76833539 Vidic_Tanja_-_Bakrove(II)_spojine_z_adipinsko_kislino_in_dusikovimi_donorskimi_ligandi.pdf Vidic_Tanja_-_Bakrove(II)_spojine_z_adipinsko_kislino_in_dusikovimi_donorskimi_ligandi.pdf 1 E11D74A8A850559FB6F916BA8E15A3F6 deece29478108438321a5bde8c2d669c1c7c3801a6f0f0873dc5bb3e494c9f66 c86fa503-0efe-11ec-a523-00155dcfd717 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=146668 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0