20.500.12556/RUL-125941 Multi-scale modelling of Lithium-ion batteries from transport phenomena to the outbreak of thermal runaway Multi-scale and multi-domain mathematical models capable of modelling main electrochemical reactions, side reactions and heat generation can reduce the time and cost of lithium-ion battery development and deployment, since these processes decisively influence performance, durability and safety of batteries. Experimental evidences clearly indicate the importance of the interplay between electric and thermal boundary conditions, cell design and applied materials, side reactions as well as safety implications of batteries, which are not yet captured to a sufficient level by simulations models. As an answer to this challenge, the paper presents an advanced multi-scale battery modelling framework that can be seamlessly integrated into multi-domain models. The key hypothesis is that nanoscopic transport phenomena and resulting heat generation decisively influence the entire chain of mechanisms that can lead to the outbreak of the thermal runaway. This is confirmed by developing a multi-scale battery modelling framework that is based on the continuous modelling approach featuring more consistent virtual representation of the electrode topology and incorporating the coupled chain of models for heat generations and side reactions. As a result, the battery modelling framework intuitively yet insightfully elucidates the entire chain of phenomena from electric and thermal boundary conditions, over cell design and properties of applied materials to solid electrolyte interphase growth, its decomposition and subsequent side reactions at the anode, cathode and the electrolyte that lead to the thermal runaway. One of key results comprises multi-level main and side reaction driven heat transfer cross-talk between the anode and the cathode. Therefore, the presented advanced multi-scale battery modelling framework represents a contribution to the advanced virtual development of batteries thereby contributing to tailoring battery design to a specific application. Li-ion battery phase separating material continuum model multi-scale modelling heat generation thermal runaway Li-ionske baterije material s fazno separacijo kontinuumski model večskalno modeliranje generacija toplote termični pobeg true false true Angleški jezik Slovenski jezik Članek v reviji 2021-04-09 15:05:33 2021-04-09 15:05:38 2022-09-05 03:53:24 0000-00-00 00:00:00 2021 0 0 22 str. Vol. 236, art. 114036 May 2021 0000-00-00 Zaloznikova Objavljeno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 621.31:519.8(045) 0196-8904 10.1016/j.enconman.2021.114036 58992387 2618919 1-s2.0-S0196890421002120-main_(1).pdf 1-s2.0-S0196890421002120-main_(1).pdf 1 8DA678ADD6AC25DA6DAC4DF902093ED4 98a4e11903848f07adbb5acce55e45753056eee289247b893abe96db6c18e9c2 ee0bda6b-197b-11ed-8aca-00155dcfd717 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=159176 https://www.sciencedirect.com/science/article/pii/S0196890421002120 0 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=141809 Fakulteta za strojništvo 0 0 0