20.500.12556/RUL-121167 Sinteza rutenijevih kompleksov s tiosemikarbazoni Synthesis of ruthenium complexes with thiosemicarbazones Sintetizirana je bila serija tiosemikarbazonov iz acetofenonov z različnimi substituenti na para- mestu in tiosemikarbazida. Nato je bila ista reakcija preizkušena z metilnimi homologi reaktantov. Pri tem je prišlo do dveh nepričakovanih ciklizacij in nastanka produktov z ogrodjem 1,2,4-triazolidina in 1,3,4-tiadiazola. Te spojine so bile uporabljene kot ligandi za sintezo organorutenijevih kompleksov s formulo [RuII(η6-p-cym)(L)Cl2] in [RuII(η6-p-cym)(L)Cl]Cl (L predstavlja uporabljen ligand). Vsi produkti so bili karakterizirani z NMR, IR spektroskopijo ter masno spektrometrijo. Devet novih struktur je bilo določenih z rentgensko difrakcijo na monokristalu. A series of thiosemicarbazones was synthesized from para- substituted acetophenones and thiosemicarbazide. Furthermore, methyl homologues of the reactants were used in the reaction. Surprisingly, two different cyclizations occurred that yielded compounds with 1,2,4-triazolydine and 1,3,4-thiadiazole scaffolds. These compounds were later used as ligands to synthesize organoruthenium half-sandwich complexes with general chemical formula [RuII(η6-p-cym)(L)Cl2] and [RuII(η6-p-cym)(L)Cl]Cl (where L is the ligand) respectively. All the products were characterized with NMR, IR spectroscopy and mass spectrometry. Nine new molecular structures were determined by X-ray diffraction. tiosemikarbazoni triazolidin-3-tioni tiadiazoli rutenijevi pol-sendvič kompleksi thiosemicarbazones triazolidine-3-thiones thiadiazoles ruthenium half-sandwich complexes true false false Slovenski jezik Angleški jezik Magistrsko delo/naloga 2020-09-30 15:30:07 2020-09-30 15:30:10 2022-09-01 04:01:52 0000-00-00 00:00:00 2020 0 0 0000-00-00 NiDoloceno NiDoloceno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 6677 36854019 Gruden_Andrej_-_Sinteza_rutenijevih_kompleksov_s_tiosemikarbazoni.pdf Gruden_Andrej_-_Sinteza_rutenijevih_kompleksov_s_tiosemikarbazoni.pdf 1 FA9FF5EBBC464E68B976AEE4E2588D8F 1b952ed06a6080403e2cf16eedbb57ce4f5533dcb59d292b395804e3541c7379 3f943d26-a1ba-11eb-a523-00155dcfd717 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=136061 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0