20.500.12556/RUL-114083 Strukturna karakterizacija izbranih derivatov indazola v prepovedanih substancah z jedrsko magnetno resonanco Structural characterization of selected indazole derivatives in illicit substances by nuclear magnetic resonance V diplomskem delu sem se ukvarjal s strukturno karakterizacijo dveh neznanih prepovedanih substanc. Posneti so bili 1H, 13C, 19F, 1H–1H COSY, 1H–13C HSQC, 1H–13C HMBC in 1H–15N HMBC NMR spektri. Na podlagi spektrov sta bila identificirana dva derivata indazola: metil 2-{[1-(5-fluoropentil)-1H-indazol-3-il]formamido}-3,3-dimetilbutanoat (5F-MDMB-PINACA) in metil 3,3-dimetil-2-{[1-(pent-4-en-1-il)-1H-indazol-3-il]formamido}butanoat (MDMB-4en-PINACA). Spektri za tako določeni strukturi so bili poiskani v literaturi in se ujemajo z eksperimentalnimi. Ključne besede: 5F-MDMB-PINACA, MDMB-4en-PINACA, NMR, karakterizacija In this thesis structural characterization of two unknown illicit substances was done. 1H, 13C, 19F, 1H–1H COSY, 1H–13C HSQC, 1H–13C HMBC and 1H–15N HMBC NMR spectra were recorded. Based on the spectra, two indazole derivatives were identified: methyl 2-{[1-(5-fluoropentyl)-1H-indazol-3-yl]formamido}-3,3-dimethylbutanoate (5F-MDMB-PINACA) and methyl 3,3‐dimethyl‐2‐{[1‐(pent‐4‐en‐1‐yl)‐1H‐indazol‐3‐yl]formamido}butanoate (MDMB-4en-PINACA). Spectral data for the compounds are in accordance with those previously reported in the literature. Keywords: 5F-MDMB-PINACA, MDMB-4en-PINACA, NMR, characterization 5F-MDMB-PINACA MDMB-4en-PINACA NMR karakterizacija 5F-MDMB-PINACA MDMB-4en-PINACA NMR characterization true false false Slovenski jezik Angleški jezik Diplomsko delo/naloga 2020-02-13 10:45:00 2020-02-13 10:45:04 2022-08-26 03:49:00 0000-00-00 00:00:00 2020 0 0 0000-00-00 NiDoloceno NiDoloceno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 6335 1538530243 Tomazic_Martin_-_Strukturna_karakterizacija_izbranih_derivatov_indazola_v_prepovedanih_substanca.pdf Tomazic_Martin_-_Strukturna_karakterizacija_izbranih_derivatov_indazola_v_prepovedanih_substanca.pdf 1 5E13DB9E2035FD9001F0FA91A4E28748 6da531c2fb1773a92d03bc9742d0c92be167ab5c80cbf71dc65d98d84822e7c4 2d45a286-a1b8-11eb-a523-00155dcfd717 https://repozitorij.uni-lj.si/Dokument.php?lang=slv&id=126198 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0