HAT-initiated fragmentation of 4-(dimethylamino)-1-((3-methylbut-2-en-1-yl)oxy)-3-phenylbut-3-en-2-oneBogataj, Andrej (Avtor) Ciber, Luka (Avtor) Petek, Nejc (Avtor) Požgan, Franc (Avtor) Svete, Jurij (Avtor) Štefane, Bogdan (Avtor) Grošelj, Uroš (Avtor) alkeneenaminonehydrogen atom transferfragmentationtetrabutylammonium decatungstatephenylacetoneAn alkene-tethered enaminone 7 was synthesized in four steps from bromoacetic acid and 3,3-dimethylallyl alcohol. The enaminone was fully characterized, including UV-Vis spectra. TBADT-catalyzed HAT of the alkene-tethered enaminone initiated a fragmentation that yielded the literature-known phenylacetone-derived enaminone. 20262026-03-13 12:23:49Članek v reviji180678UDK: 547.1.057ISSN pri članku: 1422-8599DOI: 10.3390/M2149COBISS_ID: 271571459sl