Ruthenium-catalyzed transfer hydrogenation of alkynesJankovič, Dominik (Avtor) Košmrlj, Janez (Avtor) Gazvoda, Martin (Avtor) catalystsrutheniumchemical reactionshydrocarbonshydrogentransfer reactionsA complete reduction of alkynes using a combination of [RuCl$_2$(p-cymene)]$_2$, DTBM-SEGPHOS, and a paraformaldehyde/water system as the hydrogen source was developed, affording alkanes in 52–99% yields. In addition, the preparation of alkenes from terminal alkynes and aryl iodides by a tandem process of Pd/Cu-catalyzed Sonogashira reaction followed by Ru-catalyzed transfer hydrogenation is reported, affording alkenes in 38–99% yields. This multicatalysis proceeds via three consecutive reactions and can be extended further, as shown by adding an iodine-catalyzed cis–trans alkene isomerization step.20252025-03-19 14:27:41Članek v reviji167895UDK: 547.31:66.094.25ISSN pri članku: 0022-3263DOI: 10.1021/acs.joc.4c01864COBISS_ID: 229478915sl